Studies on Telomerization of Vinyl Chloride with Carbon Tetrabromide
Тип публикации: Journal Article
Дата публикации: 1969-05-01
SCImago Q3
WOS Q2
БС1
SJR: 0.396
CiteScore: 5.9
Impact factor: 4
ISSN: 00092673, 13480634
General Chemistry
Краткое описание
The radical telomerization of vinyl chloride with carbon tetrabromide was investigated. The telomers with n=1 and 2 in Br(CHClCH2)nCBr3 were isolated and identified. The molecular weight distribution of the telomers was determined by thin-layer chromatography (TLC), and it was found that the distribution varied a little with the variation of reaction conditions. From the results of the TLC, the chain transfer constants (Cn) of polylvinyl chloride radical to carbon tetrabromide were calculated, and a monotonous increase in Cn with the increasing n was found. The effects of initial ratio of vinyl chloride to carbon tetrabromide, reaction time and temperature on the conversion of vinyl chloride and the average molecular weight of the telomer were investigated. Bromoform was also used as a telogen instead of carbon tetrabromide, and the results were compared in both systems.
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Asahara T., CHOU M. C. Studies on Telomerization of Vinyl Chloride with Carbon Tetrabromide // Bulletin of the Chemical Society of Japan. 1969. Vol. 42. No. 5. pp. 1373-1377.
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Asahara T., CHOU M. C. Studies on Telomerization of Vinyl Chloride with Carbon Tetrabromide // Bulletin of the Chemical Society of Japan. 1969. Vol. 42. No. 5. pp. 1373-1377.
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TY - JOUR
DO - 10.1246/bcsj.42.1373
UR - https://doi.org/10.1246/bcsj.42.1373
TI - Studies on Telomerization of Vinyl Chloride with Carbon Tetrabromide
T2 - Bulletin of the Chemical Society of Japan
AU - Asahara, Teruzo
AU - CHOU, M. C.
PY - 1969
DA - 1969/05/01
PB - Oxford University Press
SP - 1373-1377
IS - 5
VL - 42
SN - 0009-2673
SN - 1348-0634
ER -
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@article{1969_Asahara,
author = {Teruzo Asahara and M. C. CHOU},
title = {Studies on Telomerization of Vinyl Chloride with Carbon Tetrabromide},
journal = {Bulletin of the Chemical Society of Japan},
year = {1969},
volume = {42},
publisher = {Oxford University Press},
month = {may},
url = {https://doi.org/10.1246/bcsj.42.1373},
number = {5},
pages = {1373--1377},
doi = {10.1246/bcsj.42.1373}
}
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MLA
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Asahara, Teruzo, and M. C. CHOU. “Studies on Telomerization of Vinyl Chloride with Carbon Tetrabromide.” Bulletin of the Chemical Society of Japan, vol. 42, no. 5, May. 1969, pp. 1373-1377. https://doi.org/10.1246/bcsj.42.1373.
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