том 48 издание 4 страницы 1254-1259

Stereospecific Synthesis of Natural (+)Blastmycinone and Its Three (2R)-Diastereomers

Shinpei Aburaki
Norio Konishi
Mitsuhiro Kinoshita
Тип публикацииJournal Article
Дата публикации1975-04-01
scimago Q2
wos Q2
БС1
SJR0.678
CiteScore7.0
Impact factor3.8
ISSN00092673, 13480634
General Chemistry
Краткое описание
Natural (+)blastmycinone [(+)1a] and its three (2R)-diastereomers [(+)1b, (−)1c, and (−)1d] were synthesized through stereospecific routes via the corresponding (−)blastmycinolactol [(−)2a] and its diastereomeric hydroxylactones [(+)2b, (−)2c, and (−)2d] from methyl 4,6-O-benzylidene-3-C-butyl-3-deoxy-α-D-altropyranoside (4) prepared by the Grignard reaction of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranoside (3) with butylmagnesium chloride. By the synthesis the relative configurations of natural type of racemic blastmycinone and its all diastereomers were completely established.
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Aburaki S., Konishi N., Kinoshita M. Stereospecific Synthesis of Natural (+)Blastmycinone and Its Three (2R)-Diastereomers // Bulletin of the Chemical Society of Japan. 1975. Vol. 48. No. 4. pp. 1254-1259.
ГОСТ со всеми авторами (до 50) Скопировать
Aburaki S., Konishi N., Kinoshita M. Stereospecific Synthesis of Natural (+)Blastmycinone and Its Three (2R)-Diastereomers // Bulletin of the Chemical Society of Japan. 1975. Vol. 48. No. 4. pp. 1254-1259.
RIS |
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TY - JOUR
DO - 10.1246/bcsj.48.1254
UR - https://doi.org/10.1246/bcsj.48.1254
TI - Stereospecific Synthesis of Natural (+)Blastmycinone and Its Three (2R)-Diastereomers
T2 - Bulletin of the Chemical Society of Japan
AU - Aburaki, Shinpei
AU - Konishi, Norio
AU - Kinoshita, Mitsuhiro
PY - 1975
DA - 1975/04/01
PB - Oxford University Press
SP - 1254-1259
IS - 4
VL - 48
SN - 0009-2673
SN - 1348-0634
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{1975_Aburaki,
author = {Shinpei Aburaki and Norio Konishi and Mitsuhiro Kinoshita},
title = {Stereospecific Synthesis of Natural (+)Blastmycinone and Its Three (2R)-Diastereomers},
journal = {Bulletin of the Chemical Society of Japan},
year = {1975},
volume = {48},
publisher = {Oxford University Press},
month = {apr},
url = {https://doi.org/10.1246/bcsj.48.1254},
number = {4},
pages = {1254--1259},
doi = {10.1246/bcsj.48.1254}
}
MLA
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Aburaki, Shinpei, et al. “Stereospecific Synthesis of Natural (+)Blastmycinone and Its Three (2R)-Diastereomers.” Bulletin of the Chemical Society of Japan, vol. 48, no. 4, Apr. 1975, pp. 1254-1259. https://doi.org/10.1246/bcsj.48.1254.