Partial Reduction of Dinitroarenes to Nitroanilines with Hydrazine Hydrate
Publication type: Journal Article
Publication date: 1983-10-01
scimago Q2
wos Q2
SJR: 0.678
CiteScore: 7.0
Impact factor: 3.8
ISSN: 00092673, 13480634
General Chemistry
Abstract
Dinitroarenes containing substituents such as hydroxyl and amine groups could be conveniently reduced with 3 molar equivalents of hydrazine hydrate in presence of Raney nickel catalyst in ethanol/1,2-dichloroethane solvent mixture to give a product wherein one of the two nitro groups was reduced to the amino group. The yields of the partial reduction products are good. Under similar conditions alkoxyl substituents in the o,p-position to the nitro groups were displaced by the hydrazino group to give 2,4-dinitrophenylhydrazine as the main product. The details of the reduction reaction are described.
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GOST
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Ayyangar N. R. et al. Partial Reduction of Dinitroarenes to Nitroanilines with Hydrazine Hydrate // Bulletin of the Chemical Society of Japan. 1983. Vol. 56. No. 10. pp. 3159-3164.
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Ayyangar N. R., Kalkote U. R., Lugade A. G., Nikrad P. V., Sharma V. K. Partial Reduction of Dinitroarenes to Nitroanilines with Hydrazine Hydrate // Bulletin of the Chemical Society of Japan. 1983. Vol. 56. No. 10. pp. 3159-3164.
Cite this
RIS
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TY - JOUR
DO - 10.1246/bcsj.56.3159
UR - https://doi.org/10.1246/bcsj.56.3159
TI - Partial Reduction of Dinitroarenes to Nitroanilines with Hydrazine Hydrate
T2 - Bulletin of the Chemical Society of Japan
AU - Ayyangar, Nagaraj R.
AU - Kalkote, Uttam R.
AU - Lugade, Ananda G.
AU - Nikrad, Pandurang V.
AU - Sharma, Vasant K.
PY - 1983
DA - 1983/10/01
PB - Oxford University Press
SP - 3159-3164
IS - 10
VL - 56
SN - 0009-2673
SN - 1348-0634
ER -
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BibTex (up to 50 authors)
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@article{1983_Ayyangar,
author = {Nagaraj R. Ayyangar and Uttam R. Kalkote and Ananda G. Lugade and Pandurang V. Nikrad and Vasant K. Sharma},
title = {Partial Reduction of Dinitroarenes to Nitroanilines with Hydrazine Hydrate},
journal = {Bulletin of the Chemical Society of Japan},
year = {1983},
volume = {56},
publisher = {Oxford University Press},
month = {oct},
url = {https://doi.org/10.1246/bcsj.56.3159},
number = {10},
pages = {3159--3164},
doi = {10.1246/bcsj.56.3159}
}
Cite this
MLA
Copy
Ayyangar, Nagaraj R., et al. “Partial Reduction of Dinitroarenes to Nitroanilines with Hydrazine Hydrate.” Bulletin of the Chemical Society of Japan, vol. 56, no. 10, Oct. 1983, pp. 3159-3164. https://doi.org/10.1246/bcsj.56.3159.