Tris(trimethylsilyl)silane-mediated Reductive Decyanation and Cyano Transfer Reactions of Malononitriles
Publication type: Journal Article
Publication date: 2018-04-05
scimago Q3
wos Q4
SJR: 0.374
CiteScore: 2.8
Impact factor: 1.1
ISSN: 03667022, 13480715
General Chemistry
Abstract
Reductive decyanation reactions of malononitriles were achieved with tris(trimethylsilyl)silane as a radical mediator. The reaction proceeds via a radical chain mechanism involving a silyl radical addition to the malononitrile to form an imidoyl radical followed by α-cleavage to give a silyl isocyanide and an α-cyano radical. The reaction of a 3-butenyl-substituted malononitrile afforded a decyano/cyanosilylation product in good yield through 1,4-cyano transfer.
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15
Total citations:
15
Citations from 2025:
5
(33.34%)
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GOST
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Kawamoto T. et al. Tris(trimethylsilyl)silane-mediated Reductive Decyanation and Cyano Transfer Reactions of Malononitriles // Chemistry Letters. 2018. Vol. 47. No. 4. pp. 573-575.
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Kawamoto T., Shimaya Y., Curran D. P., Kamimura A. Tris(trimethylsilyl)silane-mediated Reductive Decyanation and Cyano Transfer Reactions of Malononitriles // Chemistry Letters. 2018. Vol. 47. No. 4. pp. 573-575.
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RIS
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TY - JOUR
DO - 10.1246/cl.171231
UR - https://doi.org/10.1246/cl.171231
TI - Tris(trimethylsilyl)silane-mediated Reductive Decyanation and Cyano Transfer Reactions of Malononitriles
T2 - Chemistry Letters
AU - Kawamoto, Takuji
AU - Shimaya, Yudai
AU - Curran, Dennis P.
AU - Kamimura, Akio
PY - 2018
DA - 2018/04/05
PB - Oxford University Press
SP - 573-575
IS - 4
VL - 47
SN - 0366-7022
SN - 1348-0715
ER -
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BibTex (up to 50 authors)
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@article{2018_Kawamoto,
author = {Takuji Kawamoto and Yudai Shimaya and Dennis P. Curran and Akio Kamimura},
title = {Tris(trimethylsilyl)silane-mediated Reductive Decyanation and Cyano Transfer Reactions of Malononitriles},
journal = {Chemistry Letters},
year = {2018},
volume = {47},
publisher = {Oxford University Press},
month = {apr},
url = {https://doi.org/10.1246/cl.171231},
number = {4},
pages = {573--575},
doi = {10.1246/cl.171231}
}
Cite this
MLA
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Kawamoto, Takuji, et al. “Tris(trimethylsilyl)silane-mediated Reductive Decyanation and Cyano Transfer Reactions of Malononitriles.” Chemistry Letters, vol. 47, no. 4, Apr. 2018, pp. 573-575. https://doi.org/10.1246/cl.171231.