SYNTHESIS OFcis- ANDtrans-2,6-DIALKYLATED PIPERIDINES THROUGH HIGHLY REGIOSELECTIVE α-ALKYNYLATION OF PYRIDINIUM SALTS AND ITS APPLICATION TO SYNTHESIS OF (±)-SOLENOPSINE A
Тип публикации: Journal Article
Дата публикации: 1984-07-05
SCImago Q3
WOS Q4
БС2
SJR: 0.276
CiteScore: 1.8
Impact factor: 1.1
ISSN: 03667022, 13480715
General Chemistry
Краткое описание
Reactions of N-methoxycarbonyl-2-alkylpyridinium salts with alkynyl Grignard reagents give exclusively 2,6-disubstituted 1,2-dihydropyridines, from which cis- and trans-2,6-dialkylated piperidines can be derived selectively. Consequently, (±)-solenopsine A is efficiently synthesized by this sequence.
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Nakazono Y., Yamaguchi R., Kawanisi M. SYNTHESIS OFcis- ANDtrans-2,6-DIALKYLATED PIPERIDINES THROUGH HIGHLY REGIOSELECTIVE α-ALKYNYLATION OF PYRIDINIUM SALTS AND ITS APPLICATION TO SYNTHESIS OF (±)-SOLENOPSINE A // Chemistry Letters. 1984. Vol. 13. No. 7. pp. 1129-1132.
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Nakazono Y., Yamaguchi R., Kawanisi M. SYNTHESIS OFcis- ANDtrans-2,6-DIALKYLATED PIPERIDINES THROUGH HIGHLY REGIOSELECTIVE α-ALKYNYLATION OF PYRIDINIUM SALTS AND ITS APPLICATION TO SYNTHESIS OF (±)-SOLENOPSINE A // Chemistry Letters. 1984. Vol. 13. No. 7. pp. 1129-1132.
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TY - JOUR
DO - 10.1246/cl.1984.1129
UR - https://doi.org/10.1246/cl.1984.1129
TI - SYNTHESIS OFcis- ANDtrans-2,6-DIALKYLATED PIPERIDINES THROUGH HIGHLY REGIOSELECTIVE α-ALKYNYLATION OF PYRIDINIUM SALTS AND ITS APPLICATION TO SYNTHESIS OF (±)-SOLENOPSINE A
T2 - Chemistry Letters
AU - Nakazono, Yutaka
AU - Yamaguchi, Ryohei
AU - Kawanisi, Mituyosi
PY - 1984
DA - 1984/07/05
PB - Oxford University Press
SP - 1129-1132
IS - 7
VL - 13
SN - 0366-7022
SN - 1348-0715
ER -
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@article{1984_Nakazono,
author = {Yutaka Nakazono and Ryohei Yamaguchi and Mituyosi Kawanisi},
title = {SYNTHESIS OFcis- ANDtrans-2,6-DIALKYLATED PIPERIDINES THROUGH HIGHLY REGIOSELECTIVE α-ALKYNYLATION OF PYRIDINIUM SALTS AND ITS APPLICATION TO SYNTHESIS OF (±)-SOLENOPSINE A},
journal = {Chemistry Letters},
year = {1984},
volume = {13},
publisher = {Oxford University Press},
month = {jul},
url = {https://doi.org/10.1246/cl.1984.1129},
number = {7},
pages = {1129--1132},
doi = {10.1246/cl.1984.1129}
}
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Nakazono, Yutaka, et al. “SYNTHESIS OFcis- ANDtrans-2,6-DIALKYLATED PIPERIDINES THROUGH HIGHLY REGIOSELECTIVE α-ALKYNYLATION OF PYRIDINIUM SALTS AND ITS APPLICATION TO SYNTHESIS OF (±)-SOLENOPSINE A.” Chemistry Letters, vol. 13, no. 7, Jul. 1984, pp. 1129-1132. https://doi.org/10.1246/cl.1984.1129.
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