Mass Spectrometry of β-Ketoesters. Some Evidence of Their Tautomerism
Publication type: Journal Article
Publication date: 2006-10-01
scimago Q4
wos Q4
SJR: 0.243
CiteScore: 1.6
Impact factor: 0.8
ISSN: 14690667, 17516838, 13561049
DOI:
10.1255/ejms.819
PubMed ID:
17404422
Spectroscopy
General Medicine
Atomic and Molecular Physics, and Optics
Abstract
Mass spectrometric evidence of tautomerism is reported for β-ketoesters. The analysis of the corresponding mass spectra has allowed specific the assignment of fragment ions to tautomers. The predictive value of this methodology is supported by the influence of a substitution pattern of these compounds on the equilibria. Experimental data are strongly supported by Austin Model 1 semi-empirical calculations, indicating that mass spectrometry could be resourced as a tool for the investigation of tautomerism of neutral species in the gas phase.
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Allegretti P. E., Castro E. A., Furlong J. J. Mass Spectrometry of β-Ketoesters. Some Evidence of Their Tautomerism // European Journal of Mass Spectrometry. 2006. Vol. 12. No. 5. pp. 317-330.
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Allegretti P. E., Castro E. A., Furlong J. J. Mass Spectrometry of β-Ketoesters. Some Evidence of Their Tautomerism // European Journal of Mass Spectrometry. 2006. Vol. 12. No. 5. pp. 317-330.
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RIS
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TY - JOUR
DO - 10.1255/ejms.819
UR - https://doi.org/10.1255/ejms.819
TI - Mass Spectrometry of β-Ketoesters. Some Evidence of Their Tautomerism
T2 - European Journal of Mass Spectrometry
AU - Allegretti, Patricia E
AU - Castro, Eduardo A.
AU - Furlong, Jorge J.P
PY - 2006
DA - 2006/10/01
PB - SAGE
SP - 317-330
IS - 5
VL - 12
PMID - 17404422
SN - 1469-0667
SN - 1751-6838
SN - 1356-1049
ER -
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BibTex (up to 50 authors)
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@article{2006_Allegretti,
author = {Patricia E Allegretti and Eduardo A. Castro and Jorge J.P Furlong},
title = {Mass Spectrometry of β-Ketoesters. Some Evidence of Their Tautomerism},
journal = {European Journal of Mass Spectrometry},
year = {2006},
volume = {12},
publisher = {SAGE},
month = {oct},
url = {https://doi.org/10.1255/ejms.819},
number = {5},
pages = {317--330},
doi = {10.1255/ejms.819}
}
Cite this
MLA
Copy
Allegretti, Patricia E., et al. “Mass Spectrometry of β-Ketoesters. Some Evidence of Their Tautomerism.” European Journal of Mass Spectrometry, vol. 12, no. 5, Oct. 2006, pp. 317-330. https://doi.org/10.1255/ejms.819.