Walter de Gruyter
Pure and Applied Chemistry
,  том 73 ,  издание 2 ,  страницы 367-371

New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations

Тип публикации: Journal Article
Дата публикации: 2001-01-01
Walter de Gruyter
scimago Q2
wos Q3
БС2
SJR: 0.426
CiteScore: 3.2
Impact factor: 2.0
ISSN: 00334545, 13653075
General Chemistry
General Chemical Engineering
Краткое описание

The reduction behavior of the novel zirconocene dichlorides, (h5-C5Me5) (h5-C 5Me4CH2CH2ER 2) ZrCl2 (ER2 = NMe2, PMe2, PPh2) , (h5-C5Me4CH2 CH2PMe2) 2ZrCl 2, and (h5-C5Me4CH2 CH2PPh2) (h5-C 5Me4CH2CH2PMe 2) ZrCl2, together with the new types of intramolecular activation of inert C-H and C-heteroatom bonds are presented and discussed. A remarkably thermally stable zirconocene alkylhydryde type framework complex (h5-C5Me5) [h5 ,s-C5Me4CH2CH 2N (Me) CH2-]ZrH, zirconocene arylhydryde complex (h5-C5Me5) [h5 ,s-C5Me4CH2CH 2P (Ph) -o-C6H4-]ZrH, tetramethylfulvene hydride-type complexes (h5-C5Me5) [h6 :h1- (CH2C5Me3 ) CH2CH2PR2]ZrH (R = Me, Ph) and (h5-C5Me4CH2 CH2PPh2) [h6:h 1- (CH2C5Me3) CH 2CH2PMe2]ZrH are reported. The first unusually thermally stable zirconocene (h5,h1-C5Me4 CH2CH2PMe2) 2 Zr with the Zr (II) center stabilized by intramolecular coordination of two Me2P-groups is described.

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Krut’ko D. P. et al. New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations // Pure and Applied Chemistry. 2001. Vol. 73. No. 2. pp. 367-371.
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Krut’ko D. P., Borzov M. V., Veksler E. N., Kirsanov R. S., Churakov A. V., Lemenovskii D. A. New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations // Pure and Applied Chemistry. 2001. Vol. 73. No. 2. pp. 367-371.
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TY - JOUR
DO - 10.1351/pac200173020367
UR - https://www.degruyter.com/document/doi/10.1351/pac200173020367/html
TI - New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations
T2 - Pure and Applied Chemistry
AU - Krut’ko, Dmitrii P.
AU - Borzov, Maxim V.
AU - Veksler, Edward N
AU - Kirsanov, Roman S.
AU - Churakov, Andrej V
AU - Lemenovskii, Dmitri A
PY - 2001
DA - 2001/01/01
PB - Walter de Gruyter
SP - 367-371
IS - 2
VL - 73
SN - 0033-4545
SN - 1365-3075
ER -
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@article{2001_Krut’ko,
author = {Dmitrii P. Krut’ko and Maxim V. Borzov and Edward N Veksler and Roman S. Kirsanov and Andrej V Churakov and Dmitri A Lemenovskii},
title = {New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations},
journal = {Pure and Applied Chemistry},
year = {2001},
volume = {73},
publisher = {Walter de Gruyter},
month = {jan},
url = {https://www.degruyter.com/document/doi/10.1351/pac200173020367/html},
number = {2},
pages = {367--371},
doi = {10.1351/pac200173020367}
}
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Krut’ko, Dmitrii P., et al. “New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations.” Pure and Applied Chemistry, vol. 73, no. 2, Jan. 2001, pp. 367-371. https://www.degruyter.com/document/doi/10.1351/pac200173020367/html.