Walter de Gruyter
Pure and Applied Chemistry
,  volume 73 ,  issue 2 ,  pages 367-371

New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations

Publication type: Journal Article
Publication date: 2001-01-01
Walter de Gruyter
scimago Q2
wos Q3
SJR: 0.426
CiteScore: 3.2
Impact factor: 2.0
ISSN: 00334545, 13653075
General Chemistry
General Chemical Engineering
Abstract

The reduction behavior of the novel zirconocene dichlorides, (h5-C5Me5) (h5-C 5Me4CH2CH2ER 2) ZrCl2 (ER2 = NMe2, PMe2, PPh2) , (h5-C5Me4CH2 CH2PMe2) 2ZrCl 2, and (h5-C5Me4CH2 CH2PPh2) (h5-C 5Me4CH2CH2PMe 2) ZrCl2, together with the new types of intramolecular activation of inert C-H and C-heteroatom bonds are presented and discussed. A remarkably thermally stable zirconocene alkylhydryde type framework complex (h5-C5Me5) [h5 ,s-C5Me4CH2CH 2N (Me) CH2-]ZrH, zirconocene arylhydryde complex (h5-C5Me5) [h5 ,s-C5Me4CH2CH 2P (Ph) -o-C6H4-]ZrH, tetramethylfulvene hydride-type complexes (h5-C5Me5) [h6 :h1- (CH2C5Me3 ) CH2CH2PR2]ZrH (R = Me, Ph) and (h5-C5Me4CH2 CH2PPh2) [h6:h 1- (CH2C5Me3) CH 2CH2PMe2]ZrH are reported. The first unusually thermally stable zirconocene (h5,h1-C5Me4 CH2CH2PMe2) 2 Zr with the Zr (II) center stabilized by intramolecular coordination of two Me2P-groups is described.

Found 

Top-30

Journals

1
Polyhedron
Polyhedron, 1, 25%
Polyhedron
1 publication, 25%
Russian Chemical Bulletin
Russian Chemical Bulletin, 1, 25%
Russian Chemical Bulletin
1 publication, 25%
Chemistry - A European Journal
Chemistry - A European Journal, 1, 25%
Chemistry - A European Journal
1 publication, 25%
ChemInform
ChemInform, 1, 25%
ChemInform
1 publication, 25%
1

Publishers

1
2
Wiley
Wiley, 2, 50%
Wiley
2 publications, 50%
Elsevier
Elsevier, 1, 25%
Elsevier
1 publication, 25%
Springer Nature
Springer Nature, 1, 25%
Springer Nature
1 publication, 25%
1
2
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
4
Share
Cite this
GOST |
Cite this
GOST Copy
Krut’ko D. P. et al. New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations // Pure and Applied Chemistry. 2001. Vol. 73. No. 2. pp. 367-371.
GOST all authors (up to 50) Copy
Krut’ko D. P., Borzov M. V., Veksler E. N., Kirsanov R. S., Churakov A. V., Lemenovskii D. A. New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations // Pure and Applied Chemistry. 2001. Vol. 73. No. 2. pp. 367-371.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1351/pac200173020367
UR - https://www.degruyter.com/document/doi/10.1351/pac200173020367/html
TI - New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations
T2 - Pure and Applied Chemistry
AU - Krut’ko, Dmitrii P.
AU - Borzov, Maxim V.
AU - Veksler, Edward N
AU - Kirsanov, Roman S.
AU - Churakov, Andrej V
AU - Lemenovskii, Dmitri A
PY - 2001
DA - 2001/01/01
PB - Walter de Gruyter
SP - 367-371
IS - 2
VL - 73
SN - 0033-4545
SN - 1365-3075
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2001_Krut’ko,
author = {Dmitrii P. Krut’ko and Maxim V. Borzov and Edward N Veksler and Roman S. Kirsanov and Andrej V Churakov and Dmitri A Lemenovskii},
title = {New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations},
journal = {Pure and Applied Chemistry},
year = {2001},
volume = {73},
publisher = {Walter de Gruyter},
month = {jan},
url = {https://www.degruyter.com/document/doi/10.1351/pac200173020367/html},
number = {2},
pages = {367--371},
doi = {10.1351/pac200173020367}
}
MLA
Cite this
MLA Copy
Krut’ko, Dmitrii P., et al. “New metallocenes of early transition metals with functional groups in organic ligands. Red-ox transformations.” Pure and Applied Chemistry, vol. 73, no. 2, Jan. 2001, pp. 367-371. https://www.degruyter.com/document/doi/10.1351/pac200173020367/html.