volume 103 issue 3 pages 175-185

Partitioning and speciation of Pu in the sedimentary rocks aquifer from the deep liquid nuclear waste disposal

Publication typeJournal Article
Publication date2014-12-18
scimago Q4
wos Q2
SJR0.268
CiteScore3.0
Impact factor1.7
ISSN00338230, 21933405
Physical and Theoretical Chemistry
Abstract

Plutonium partitioning and speciation was studied under the conditions of a liquid nuclear waste repository site. The dominating effect of corrosion products (Fe and Cr) oxides on plutonium partitioning was established in batch sorption tests at 150 ℃ and by using sequential extraction. Various techniques including Mössbauer spectrometry, XRD and TEM were used to characterize Fe/Cr oxide phases that form both precipitates and surface coatings which sorb plutonium. The sorption and speciation of plutonium was modeled thermodynamically using Pourbaix diagram that takes into account both surface complexation reaction and precipitation of insoluble PuO2.

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Kalmykov S. N. et al. Partitioning and speciation of Pu in the sedimentary rocks aquifer from the deep liquid nuclear waste disposal // Radiochimica Acta. 2014. Vol. 103. No. 3. pp. 175-185.
GOST all authors (up to 50) Copy
Vlasova I. E., Romanchuk A. Yu., Zakharova E. V., Volkova A. G., Presnyakov I. A. Partitioning and speciation of Pu in the sedimentary rocks aquifer from the deep liquid nuclear waste disposal // Radiochimica Acta. 2014. Vol. 103. No. 3. pp. 175-185.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1515/RACT-2014-2344
UR - https://www.degruyter.com/document/doi/10.1515/ract-2014-2344/html
TI - Partitioning and speciation of Pu in the sedimentary rocks aquifer from the deep liquid nuclear waste disposal
T2 - Radiochimica Acta
AU - Vlasova, Irina E
AU - Romanchuk, Anna Yu
AU - Zakharova, Elena V.
AU - Volkova, Anna G
AU - Presnyakov, Igor A.
PY - 2014
DA - 2014/12/18
PB - Walter de Gruyter
SP - 175-185
IS - 3
VL - 103
SN - 0033-8230
SN - 2193-3405
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Kalmykov,
author = {Irina E Vlasova and Anna Yu Romanchuk and Elena V. Zakharova and Anna G Volkova and Igor A. Presnyakov},
title = {Partitioning and speciation of Pu in the sedimentary rocks aquifer from the deep liquid nuclear waste disposal},
journal = {Radiochimica Acta},
year = {2014},
volume = {103},
publisher = {Walter de Gruyter},
month = {dec},
url = {https://www.degruyter.com/document/doi/10.1515/ract-2014-2344/html},
number = {3},
pages = {175--185},
doi = {10.1515/RACT-2014-2344}
}
MLA
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MLA Copy
Kalmykov, Stepan N., et al. “Partitioning and speciation of Pu in the sedimentary rocks aquifer from the deep liquid nuclear waste disposal.” Radiochimica Acta, vol. 103, no. 3, Dec. 2014, pp. 175-185. https://www.degruyter.com/document/doi/10.1515/ract-2014-2344/html.