Macrocyclic tetrakis-phosphines and their copper(I) complexes
Elvira Musina
1
,
Tatiana I Wittmann
1
,
Alexey B. Dobrynin
1
,
Andrey A Karasik
1
,
Peter Lönnecke
2
,
Evamarie Hey-Hawkins
2
1
Тип публикации: Journal Article
Дата публикации: 2017-01-23
scimago Q2
wos Q3
БС2
SJR: 0.426
CiteScore: 3.2
Impact factor: 2.0
ISSN: 00334545, 13653075
General Chemistry
General Chemical Engineering
Краткое описание
A series of mono-, di- and tetranuclear copper(I) complexes with macrocyclic 14-, 16-, 18- and 20-membered tetrakis-phosphine ligands (P4N2) was obtained and fully characterized including single crystal X-ray diffraction. The 14-membered P4N2 macrocycles form very stable cationic mononuclear tetraphospha-coordinated copper(I) complexes, whereas their higher 16-, 18- and 20-membered homologues give neutral dinuclear [Cu2I2L] complexes under the same conditions. An unusual tetranuclear complex with two three- and two four-coordinated copper(I) atoms was obtained from 16-PMes 4NCH2CH2Py-2 2 and copper(I) iodide. This is the first example of N-coordination of cyclic aminomethylphosphines towards “soft” copper(I).
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ГОСТ
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Musina E. et al. Macrocyclic tetrakis-phosphines and their copper(I) complexes // Pure and Applied Chemistry. 2017. Vol. 89. No. 3. pp. 331-339.
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Musina E., Wittmann T. I., Dobrynin A. B., Karasik A. A., Sinyashin O. G., Lönnecke P., Hey-Hawkins E. Macrocyclic tetrakis-phosphines and their copper(I) complexes // Pure and Applied Chemistry. 2017. Vol. 89. No. 3. pp. 331-339.
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TY - JOUR
DO - 10.1515/pac-2016-1013
UR - https://www.degruyter.com/document/doi/10.1515/pac-2016-1013/html
TI - Macrocyclic tetrakis-phosphines and their copper(I) complexes
T2 - Pure and Applied Chemistry
AU - Musina, Elvira
AU - Wittmann, Tatiana I
AU - Dobrynin, Alexey B.
AU - Karasik, Andrey A
AU - Sinyashin, Oleg G.
AU - Lönnecke, Peter
AU - Hey-Hawkins, Evamarie
PY - 2017
DA - 2017/01/23
PB - Walter de Gruyter
SP - 331-339
IS - 3
VL - 89
SN - 0033-4545
SN - 1365-3075
ER -
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@article{2017_Musina,
author = {Elvira Musina and Tatiana I Wittmann and Alexey B. Dobrynin and Andrey A Karasik and Oleg G. Sinyashin and Peter Lönnecke and Evamarie Hey-Hawkins},
title = {Macrocyclic tetrakis-phosphines and their copper(I) complexes},
journal = {Pure and Applied Chemistry},
year = {2017},
volume = {89},
publisher = {Walter de Gruyter},
month = {jan},
url = {https://www.degruyter.com/document/doi/10.1515/pac-2016-1013/html},
number = {3},
pages = {331--339},
doi = {10.1515/pac-2016-1013}
}
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MLA
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Musina, Elvira, et al. “Macrocyclic tetrakis-phosphines and their copper(I) complexes.” Pure and Applied Chemistry, vol. 89, no. 3, Jan. 2017, pp. 331-339. https://www.degruyter.com/document/doi/10.1515/pac-2016-1013/html.