Pure and Applied Chemistry

, volume 89 , issue 3 , pages 331-339

Macrocyclic tetrakis-phosphines and their copper(I) complexes

Elvira Musina ¹

Tatiana I Wittmann ¹

Alexey B. Dobrynin ¹

Andrey A Karasik ¹

Oleg G. Sinyashin ¹

Peter Lönnecke ²

Evamarie Hey-Hawkins ²

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A.E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Arbuzov-str. 8, 420088 Kazan, Russia

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Faculty of Chemistry and Mineralogy, Institute of Inorganic Chemistry, Leipzig University, Johannisallee 29, 04103 Leipzig, Germany |

Publication type: Journal Article

Publication date: 2017-01-23

Walter de Gruyter

Pure and Applied Chemistry

scimago Q2

wos Q3

SJR: 0.426

CiteScore: 3.2

Impact factor: 2.0

ISSN: 00334545, 13653075

DOI: 10.1515/pac-2016-1013

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General Chemistry

General Chemical Engineering

Abstract

A series of mono-, di- and tetranuclear copper(I) complexes with macrocyclic 14-, 16-, 18- and 20-membered tetrakis-phosphine ligands (P₄N₂) was obtained and fully characterized including single crystal X-ray diffraction. The 14-membered P₄N₂ macrocycles form very stable cationic mononuclear tetraphospha-coordinated copper(I) complexes, whereas their higher 16-, 18- and 20-membered homologues give neutral dinuclear [Cu₂I₂L] complexes under the same conditions. An unusual tetranuclear complex with two three- and two four-coordinated copper(I) atoms was obtained from 16-P^Mes ₄N^CH2CH2Py-2 ₂ and copper(I) iodide. This is the first example of N-coordination of cyclic aminomethylphosphines towards “soft” copper(I).

Found

6 citations

Karasik Andrey

DSc in Chemistry, professor, associate member of the Russian Academy of Sciences

224 publications, 2 599 citations

h-index: 26

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

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1 citation

Beloglazkina Elena

DSc in Chemistry, professor

296 publications, 3 248 citations, 11 reviews

h-index: 29

Lomonosov Moscow State University

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284 publications, 4 398 citations, 65 reviews

h-index: 34

Lomonosov Moscow State University

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

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Lanthanides

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1 citation

Strelnik Igor

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PhD in Chemistry

60 publications, 816 citations, 5 reviews

h-index: 17

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

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"Smart" materials

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1 citation

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44 publications, 625 citations

h-index: 14

Saint Petersburg State University

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Osipov Sergey

DSc in Chemistry

138 publications, 2 739 citations, 3 reviews

h-index: 29

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

1 citation

Gazizov Almir

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DSc in Chemistry

157 publications, 889 citations, 23 reviews

h-index: 14

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

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Dotsenko Viktor

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North Caucasus Federal University

Kuban State University

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Musin Lenar

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Zagidullin Almaz

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PhD in Chemistry

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A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

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Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials

Coordination chemistry of phosphorus

Organoelement chemistry

Organophosphorus chemistry

Synthesis of chiral phosphorus-containing ligands

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Aksenov Aleksandr

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North Caucasus Federal University

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Sosnovskikh Vyacheslav

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Ural Federal University

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h-index: 25

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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Tikhomirov Alexander

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Mendeleev University of Chemical Technology of Russia

Gause Institute of New Antibiotics

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A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

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Ural Federal University

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GOST |

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GOST Copy

Musina E. et al. Macrocyclic tetrakis-phosphines and their copper(I) complexes // Pure and Applied Chemistry. 2017. Vol. 89. No. 3. pp. 331-339.

GOST all authors (up to 50) Copy

Musina E., Wittmann T. I., Dobrynin A. B., Karasik A. A., Sinyashin O. G., Lönnecke P., Hey-Hawkins E. Macrocyclic tetrakis-phosphines and their copper(I) complexes // Pure and Applied Chemistry. 2017. Vol. 89. No. 3. pp. 331-339.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1515/pac-2016-1013

UR - https://www.degruyter.com/document/doi/10.1515/pac-2016-1013/html

TI - Macrocyclic tetrakis-phosphines and their copper(I) complexes

T2 - Pure and Applied Chemistry

AU - Musina, Elvira

AU - Wittmann, Tatiana I

AU - Dobrynin, Alexey B.

AU - Karasik, Andrey A

AU - Sinyashin, Oleg G.

AU - Lönnecke, Peter

AU - Hey-Hawkins, Evamarie

PY - 2017

DA - 2017/01/23

PB - Walter de Gruyter

SP - 331-339

IS - 3

VL - 89

SN - 0033-4545

SN - 1365-3075

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2017_Musina,

author = {Elvira Musina and Tatiana I Wittmann and Alexey B. Dobrynin and Andrey A Karasik and Oleg G. Sinyashin and Peter Lönnecke and Evamarie Hey-Hawkins},

title = {Macrocyclic tetrakis-phosphines and their copper(I) complexes},

journal = {Pure and Applied Chemistry},

year = {2017},

volume = {89},

publisher = {Walter de Gruyter},

month = {jan},

url = {https://www.degruyter.com/document/doi/10.1515/pac-2016-1013/html},

number = {3},

pages = {331--339},

doi = {10.1515/pac-2016-1013}

}

MLA

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MLA Copy

Musina, Elvira, et al. “Macrocyclic tetrakis-phosphines and their copper(I) complexes.” Pure and Applied Chemistry, vol. 89, no. 3, Jan. 2017, pp. 331-339. https://www.degruyter.com/document/doi/10.1515/pac-2016-1013/html.

Publisher

Walter de Gruyter

Journal

Pure and Applied Chemistry

scimago Q2

wos Q3

SJR

0.426

CiteScore

3.2

Impact factor

2.0

ISSN

00334545 (Print)

13653075 (Electronic)

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