Silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with malonyl peroxides in solvent-free conditions
Oleg V Bityukov
1, 2
,
Vera A. Vil’
1, 2, 3
,
Valentina M Merkulova
1
,
Gennady I. Nikishin
1
,
Alexander O. Terent’ev
1, 2, 3
Publication type: Journal Article
Publication date: 2017-05-24
scimago Q2
wos Q3
SJR: 0.426
CiteScore: 3.2
Impact factor: 2.0
ISSN: 00334545, 13653075
General Chemistry
General Chemical Engineering
Abstract
For the first time silica gel was observed to activate peroxides in oxidative coupling reactions. Here we report silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with cyclic diacyl peroxides affording α-acyloxy derivatives with 100% atom efficiency. The highest yields of coupling products were achieved in solvent free conditions. C–O coupling products were prepared in yields up to 86%.
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15
Total citations:
15
Citations from 2024:
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GOST
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Bityukov O. V. et al. Silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with malonyl peroxides in solvent-free conditions // Pure and Applied Chemistry. 2017. Vol. 90. No. 1. pp. 7-20.
GOST all authors (up to 50)
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Bityukov O. V., Vil’ V. A., Merkulova V. M., Nikishin G. I., Terent’ev A. O. Silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with malonyl peroxides in solvent-free conditions // Pure and Applied Chemistry. 2017. Vol. 90. No. 1. pp. 7-20.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1515/pac-2017-0312
UR - https://doi.org/10.1515/pac-2017-0312
TI - Silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with malonyl peroxides in solvent-free conditions
T2 - Pure and Applied Chemistry
AU - Bityukov, Oleg V
AU - Vil’, Vera A.
AU - Merkulova, Valentina M
AU - Nikishin, Gennady I.
AU - Terent’ev, Alexander O.
PY - 2017
DA - 2017/05/24
PB - Walter de Gruyter
SP - 7-20
IS - 1
VL - 90
SN - 0033-4545
SN - 1365-3075
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Bityukov,
author = {Oleg V Bityukov and Vera A. Vil’ and Valentina M Merkulova and Gennady I. Nikishin and Alexander O. Terent’ev},
title = {Silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with malonyl peroxides in solvent-free conditions},
journal = {Pure and Applied Chemistry},
year = {2017},
volume = {90},
publisher = {Walter de Gruyter},
month = {may},
url = {https://doi.org/10.1515/pac-2017-0312},
number = {1},
pages = {7--20},
doi = {10.1515/pac-2017-0312}
}
Cite this
MLA
Copy
Bityukov, Oleg V., et al. “Silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with malonyl peroxides in solvent-free conditions.” Pure and Applied Chemistry, vol. 90, no. 1, May. 2017, pp. 7-20. https://doi.org/10.1515/pac-2017-0312.