Halogen bonding in crystals of free 1,2-diiodo-ethene (C2 H2 I2 ) and its π-complex [CpMn(CO)2 ](π-C2 H2 I2 )
Yury V. Torubaev
1
,
Ivan V Skabitsky
1
Publication type: Journal Article
Publication date: 2020-11-05
SJR: —
CiteScore: —
Impact factor: —
ISSN: 21944946, 21967105
Inorganic Chemistry
Condensed Matter Physics
General Materials Science
Abstract
1,2-trans-diiodo-ethene (C2H2I2) – is an overlooked halogen bond donor, which demonstrate the distinct similarity of the geometry and directionality of I···I halogen bonds around the iodine atoms in its native and CpMn(CO)2(C2H2I2) π-complex crystals. Distortion of the planar geometry of C2H2I2 upon the π-coordination result the distortion of the native planar layered geometry of C2H2I2, so that [CpMn(CO)2](π-C2H2I2) features more complex I···I XB assisted 3D network. Unusual structural parallels between the native C2H2I2 crystals and solid iodine are discussed.
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Torubaev Y. V., Skabitsky I. V. Halogen bonding in crystals of free 1,2-diiodo-ethene (C2H2I2) and its π-complex [CpMn(CO)2](π-C2H2I2) // Zeitschrift fur Kristallographie - Crystalline Materials. 2020. Vol. 235. No. 12. pp. 599-607.
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Torubaev Y. V., Skabitsky I. V. Halogen bonding in crystals of free 1,2-diiodo-ethene (C2H2I2) and its π-complex [CpMn(CO)2](π-C2H2I2) // Zeitschrift fur Kristallographie - Crystalline Materials. 2020. Vol. 235. No. 12. pp. 599-607.
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TY - JOUR
DO - 10.1515/zkri-2020-0064
UR - https://www.degruyter.com/document/doi/10.1515/zkri-2020-0064/html
TI - Halogen bonding in crystals of free 1,2-diiodo-ethene (C2H2I2) and its π-complex [CpMn(CO)2](π-C2H2I2)
T2 - Zeitschrift fur Kristallographie - Crystalline Materials
AU - Torubaev, Yury V.
AU - Skabitsky, Ivan V
PY - 2020
DA - 2020/11/05
PB - Walter de Gruyter
SP - 599-607
IS - 12
VL - 235
SN - 2194-4946
SN - 2196-7105
ER -
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BibTex (up to 50 authors)
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@article{2020_Torubaev,
author = {Yury V. Torubaev and Ivan V Skabitsky},
title = {Halogen bonding in crystals of free 1,2-diiodo-ethene (C2H2I2) and its π-complex [CpMn(CO)2](π-C2H2I2)},
journal = {Zeitschrift fur Kristallographie - Crystalline Materials},
year = {2020},
volume = {235},
publisher = {Walter de Gruyter},
month = {nov},
url = {https://www.degruyter.com/document/doi/10.1515/zkri-2020-0064/html},
number = {12},
pages = {599--607},
doi = {10.1515/zkri-2020-0064}
}
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MLA
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Torubaev, Yury V., and Ivan V Skabitsky. “Halogen bonding in crystals of free 1,2-diiodo-ethene (C2H2I2) and its π-complex [CpMn(CO)2](π-C2H2I2).” Zeitschrift fur Kristallographie - Crystalline Materials, vol. 235, no. 12, Nov. 2020, pp. 599-607. https://www.degruyter.com/document/doi/10.1515/zkri-2020-0064/html.