,
volume 30
,
issue 3
,
pages 347-355
Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen / Mass-spectrometric Determination of Bond Dissoziation Energies in Organosilicon Compounds
Publication type: Journal Article
Publication date: 1975-03-01
scimago Q3
wos Q3
SJR: 0.253
CiteScore: 3.0
Impact factor: 1.3
ISSN: 09320784, 18657109
Physical and Theoretical Chemistry
General Physics and Astronomy
Mathematical Physics
Abstract
The appearance potentials for a large number of organosilicon ions have been measured. Combination of these values with thermochemical heats of combustion allow the determination of bond energy terms which may be used to calculate heats of formation for all silicon compounds containing hydrogen, alkyl and chlorine ligands. The bond dissoziation energies D(Si - H)= 89 ± 4, D(Si - C) = 85 ± 4 and D (Si - Si) =75 ± 8 kcal/Mol were found to be independent of the number of methylgroups attached to silicon. In addition the Si - Cl bond energy was found to be 116 and 104 kcal/Mol in (CH3)3SiCl and Cl3SiCl respectively.
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64
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GOST
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Potzinger P., Ritter A., Krause J. Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen / Mass-spectrometric Determination of Bond Dissoziation Energies in Organosilicon Compounds // Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. 1975. Vol. 30. No. 3. pp. 347-355.
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Potzinger P., Ritter A., Krause J. Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen / Mass-spectrometric Determination of Bond Dissoziation Energies in Organosilicon Compounds // Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. 1975. Vol. 30. No. 3. pp. 347-355.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1515/zna-1975-0314
UR - https://doi.org/10.1515/zna-1975-0314
TI - Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen / Mass-spectrometric Determination of Bond Dissoziation Energies in Organosilicon Compounds
T2 - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
AU - Potzinger, P
AU - Ritter, A.
AU - Krause, J.
PY - 1975
DA - 1975/03/01
PB - Walter de Gruyter
SP - 347-355
IS - 3
VL - 30
SN - 0932-0784
SN - 1865-7109
ER -
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BibTex (up to 50 authors)
Copy
@article{1975_Potzinger,
author = {P Potzinger and A. Ritter and J. Krause},
title = {Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen / Mass-spectrometric Determination of Bond Dissoziation Energies in Organosilicon Compounds},
journal = {Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences},
year = {1975},
volume = {30},
publisher = {Walter de Gruyter},
month = {mar},
url = {https://doi.org/10.1515/zna-1975-0314},
number = {3},
pages = {347--355},
doi = {10.1515/zna-1975-0314}
}
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MLA
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Potzinger, P., et al. “Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen / Mass-spectrometric Determination of Bond Dissoziation Energies in Organosilicon Compounds.” Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, vol. 30, no. 3, Mar. 1975, pp. 347-355. https://doi.org/10.1515/zna-1975-0314.