International Journal of Electrochemical Science, volume 15, issue 3, pages 2216-2225
Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane
Publication type: Journal Article
Publication date: 2020-03-01
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.5
ISSN: 14523981
Electrochemistry
Abstract
The present work studies the solid-state lithium-ion full cell Li4Ti5O12/LiFePO4 with propylene carbonate swollen lithiated Nafion membrane (Li-Nafion) as both electrolyte and separator, and lithiated Nafion dispersion – as a binder. The advantage of this cell is single-ion lithium conductivity of the polymer electrolyte preventing its polarisation, as well as the absence of a liquid phase and negligible vapour pressure of the high-boiling-point plasticiser increasing the safety of the device. The galvanostatic charge/discharge tests examined the electrochemical performance of the full cell, as well as Li/Li4Ti5O12 and Li/LiFePO4 half-cells. With a commonly used mass ratio of composite electrodes (active material/carbon black/binder of 80:10:10), the discharge capacity of the full cell Li4Ti5O12/LiNafion/LiFePO4 as studied for the first time was about 70 mAh g -1 at 50th charge-discharge cycle at coulombic efficiency of 99%. A more proper plasticiser and optimisation of the mass ratio of the components of the electrodes can render such a cell suitable for application in LIBs with enhanced safety.
Top-30
Citations by journals
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2
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Russian Chemical Reviews
2 publications, 12.5%
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Solid State Ionics
2 publications, 12.5%
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Polymers
2 publications, 12.5%
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Membranes and Membrane Technologies
1 publication, 6.25%
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Journal of Alloys and Compounds
1 publication, 6.25%
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Electrochimica Acta
1 publication, 6.25%
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ACS applied materials & interfaces
1 publication, 6.25%
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Journal of Materials Chemistry A
1 publication, 6.25%
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ACS Applied Energy Materials
1 publication, 6.25%
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Coatings
1 publication, 6.25%
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Journal of Physical Chemistry C
1 publication, 6.25%
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Processes
1 publication, 6.25%
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Batteries
1 publication, 6.25%
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2
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Citations by publishers
1
2
3
4
5
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Multidisciplinary Digital Publishing Institute (MDPI)
5 publications, 31.25%
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Elsevier
4 publications, 25%
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American Chemical Society (ACS)
3 publications, 18.75%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 12.5%
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Pleiades Publishing
1 publication, 6.25%
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Royal Society of Chemistry (RSC)
1 publication, 6.25%
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1
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Evshchik E. Yu. et al. Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane // International Journal of Electrochemical Science. 2020. Vol. 15. No. 3. pp. 2216-2225.
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Evshchik E. Yu., Sanginov E. A., Kayumov R. R., Zhuravlev V. D., Bushkova O. V., Dobrovolsky Y. A. Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane // International Journal of Electrochemical Science. 2020. Vol. 15. No. 3. pp. 2216-2225.
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TY - JOUR
DO - 10.20964/2020.03.06
UR - https://linkinghub.elsevier.com/retrieve/pii/S1452398123103907
TI - Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane
T2 - International Journal of Electrochemical Science
AU - Evshchik, Elizaveta Yu
AU - Sanginov, Evgeny A
AU - Kayumov, Ruslan R
AU - Zhuravlev, Viktor D
AU - Bushkova, Olga V
AU - Dobrovolsky, Yury A
PY - 2020
DA - 2020/03/01 00:00:00
PB - Elsevier
SP - 2216-2225
IS - 3
VL - 15
SN - 1452-3981
ER -
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@article{2020_Evshchik,
author = {Elizaveta Yu Evshchik and Evgeny A Sanginov and Ruslan R Kayumov and Viktor D Zhuravlev and Olga V Bushkova and Yury A Dobrovolsky},
title = {Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane},
journal = {International Journal of Electrochemical Science},
year = {2020},
volume = {15},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1452398123103907},
number = {3},
pages = {2216--2225},
doi = {10.20964/2020.03.06}
}
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Evshchik, Elizaveta Yu., et al. “Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane.” International Journal of Electrochemical Science, vol. 15, no. 3, Mar. 2020, pp. 2216-2225. https://linkinghub.elsevier.com/retrieve/pii/S1452398123103907.
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