International Journal of Electrochemical Science, volume 15, issue 3, pages 2216-2225

Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane

Elizaveta Yu Evshchik
Evgeny A Sanginov
Ruslan R Kayumov
Viktor D Zhuravlev
Olga V Bushkova
Yury A Dobrovolsky
Publication typeJournal Article
Publication date2020-03-01
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor1.5
ISSN14523981
Electrochemistry
Abstract
The present work studies the solid-state lithium-ion full cell Li4Ti5O12/LiFePO4 with propylene carbonate swollen lithiated Nafion membrane (Li-Nafion) as both electrolyte and separator, and lithiated Nafion dispersion – as a binder. The advantage of this cell is single-ion lithium conductivity of the polymer electrolyte preventing its polarisation, as well as the absence of a liquid phase and negligible vapour pressure of the high-boiling-point plasticiser increasing the safety of the device. The galvanostatic charge/discharge tests examined the electrochemical performance of the full cell, as well as Li/Li4Ti5O12 and Li/LiFePO4 half-cells. With a commonly used mass ratio of composite electrodes (active material/carbon black/binder of 80:10:10), the discharge capacity of the full cell Li4Ti5O12/LiNafion/LiFePO4 as studied for the first time was about 70 mAh g -1 at 50th charge-discharge cycle at coulombic efficiency of 99%. A more proper plasticiser and optimisation of the mass ratio of the components of the electrodes can render such a cell suitable for application in LIBs with enhanced safety.

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GOST |
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GOST Copy
Evshchik E. Yu. et al. Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane // International Journal of Electrochemical Science. 2020. Vol. 15. No. 3. pp. 2216-2225.
GOST all authors (up to 50) Copy
Evshchik E. Yu., Sanginov E. A., Kayumov R. R., Zhuravlev V. D., Bushkova O. V., Dobrovolsky Y. A. Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane // International Journal of Electrochemical Science. 2020. Vol. 15. No. 3. pp. 2216-2225.
RIS |
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RIS Copy
TY - JOUR
DO - 10.20964/2020.03.06
UR - https://linkinghub.elsevier.com/retrieve/pii/S1452398123103907
TI - Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane
T2 - International Journal of Electrochemical Science
AU - Evshchik, Elizaveta Yu
AU - Sanginov, Evgeny A
AU - Kayumov, Ruslan R
AU - Zhuravlev, Viktor D
AU - Bushkova, Olga V
AU - Dobrovolsky, Yury A
PY - 2020
DA - 2020/03/01 00:00:00
PB - Elsevier
SP - 2216-2225
IS - 3
VL - 15
SN - 1452-3981
ER -
BibTex |
Cite this
BibTex Copy
@article{2020_Evshchik,
author = {Elizaveta Yu Evshchik and Evgeny A Sanginov and Ruslan R Kayumov and Viktor D Zhuravlev and Olga V Bushkova and Yury A Dobrovolsky},
title = {Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane},
journal = {International Journal of Electrochemical Science},
year = {2020},
volume = {15},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1452398123103907},
number = {3},
pages = {2216--2225},
doi = {10.20964/2020.03.06}
}
MLA
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MLA Copy
Evshchik, Elizaveta Yu., et al. “Li4Ti5O12/LiFePO4 Solid-State Lithium-Ion Full Cell with LithiatedNafion membrane.” International Journal of Electrochemical Science, vol. 15, no. 3, Mar. 2020, pp. 2216-2225. https://linkinghub.elsevier.com/retrieve/pii/S1452398123103907.
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