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Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst
Тип публикации: Journal Article
Дата публикации: 2007-10-29
SJR: 0.514
CiteScore: —
Impact factor: 1.8
ISSN: 12944475, 19538189
General Chemical Engineering
Energy Engineering and Power Technology
Fuel Technology
Краткое описание
Hydroformylation of olefins has been performed with a system based on cobalt and pyridine ligands in non-aqueous ionic liquids. In this work, a new approach was developed to recycle the cobalt catalyst without the use of chemicals. For 1-hexene, activity of the [ Co2 (CO)8 ] /Pyridine(2 eq)/[BMIM][ NTf2 ] at 100 bar and 130°C can reach 110 h-1 with a selectivity for aldehydes of up to 87% (linear to branched ratio being around 1.8). The recycling of the ionic liquid phase was performed several times without loss of activity or selectivity.
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ГОСТ
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Magna L. et al. Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst // Oil and Gas Science and Technology. 2007. Vol. 62. No. 6. pp. 775-780.
ГОСТ со всеми авторами (до 50)
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Magna L., Harry S., Proriol D., Saussine L., Olivier-Bourbigou H. Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst // Oil and Gas Science and Technology. 2007. Vol. 62. No. 6. pp. 775-780.
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RIS
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TY - JOUR
DO - 10.2516/ogst:2007052
UR - https://doi.org/10.2516/ogst:2007052
TI - Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst
T2 - Oil and Gas Science and Technology
AU - Magna, L.
AU - Harry, S.
AU - Proriol, David
AU - Saussine, L.
AU - Olivier-Bourbigou, H
PY - 2007
DA - 2007/10/29
PB - Editions Technip
SP - 775-780
IS - 6
VL - 62
SN - 1294-4475
SN - 1953-8189
ER -
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BibTex (до 50 авторов)
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@article{2007_Magna,
author = {L. Magna and S. Harry and David Proriol and L. Saussine and H Olivier-Bourbigou},
title = {Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst},
journal = {Oil and Gas Science and Technology},
year = {2007},
volume = {62},
publisher = {Editions Technip},
month = {oct},
url = {https://doi.org/10.2516/ogst:2007052},
number = {6},
pages = {775--780},
doi = {10.2516/ogst:2007052}
}
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MLA
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Magna, L., et al. “Hydroformylation of 1-hexene with a Cobalt Catalyst in Ionic Liquids: a New Efficient Approach for Generation and Recycling of the Catalyst.” Oil and Gas Science and Technology, vol. 62, no. 6, Oct. 2007, pp. 775-780. https://doi.org/10.2516/ogst:2007052.
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