Moscow University Chemistry Bulletin

, том 66 , издание 1 , страницы 43-46

Ionselective electrodes based on adamantylthiacalix[4]arenes for alkali cations determination

M Yu Nemilova ¹

N V Shvedene ¹

K V Puchnin ¹

E A Shokova ¹

V V Kovalev ¹

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Divisions of Analytical and Petroleum Chemistry, Chemistry Department, Moscow State University, Moscow, Russia |

Тип публикации: Journal Article

Дата публикации: 2011-02-01

Pleiades Publishing

Moscow University Chemistry Bulletin

scimago Q4

wos Q4

БС3

SJR: 0.153

CiteScore: 1.1

Impact factor: 0.5

ISSN: 00271314, 19350260

DOI: 10.3103/S002713141101007X

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General Chemistry

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The possibility of using three derivatives of p-R-thiacalix[4]arene: tetraethyl ester of p-(1-adamantyl)thiacalix[4]arene acid (I) and asymmetric p-tert-buthylcalix[4]-p-R-thiacalix[4]arene “molecular tubes” [R = tert-Bu(II), 1-adamantyl(III)] as ionophores in PVC-membrane ISEs for the determination of Na+, K+ and Rb+ ions was studied. It was found that an electrode based on thiacalix[4]arene (I) exhibited high selectivity toward Na+ ions, and electrodes with (II) and (III) demonstrated a good potentiometric response of the Rb+ ion; Rb+ can be determined in the presence of excess amounts Na+ and K+.

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Nemilova M. Yu. et al. Ionselective electrodes based on adamantylthiacalix[4]arenes for alkali cations determination // Moscow University Chemistry Bulletin. 2011. Vol. 66. No. 1. pp. 43-46.

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Nemilova M. Yu., Shvedene N. V., Puchnin K. V., Shokova E. A., Kovalev V. V. Ionselective electrodes based on adamantylthiacalix[4]arenes for alkali cations determination // Moscow University Chemistry Bulletin. 2011. Vol. 66. No. 1. pp. 43-46.

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TY - JOUR

DO - 10.3103/S002713141101007X

UR - https://doi.org/10.3103/S002713141101007X

TI - Ionselective electrodes based on adamantylthiacalix[4]arenes for alkali cations determination

T2 - Moscow University Chemistry Bulletin

AU - Nemilova, M Yu

AU - Shvedene, N V

AU - Puchnin, K V

AU - Shokova, E A

AU - Kovalev, V V

PY - 2011

DA - 2011/02/01

PB - Pleiades Publishing

SP - 43-46

IS - 1

VL - 66

SN - 0027-1314

SN - 1935-0260

ER -

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@article{2011_Nemilova,

author = {M Yu Nemilova and N V Shvedene and K V Puchnin and E A Shokova and V V Kovalev},

title = {Ionselective electrodes based on adamantylthiacalix[4]arenes for alkali cations determination},

journal = {Moscow University Chemistry Bulletin},

year = {2011},

volume = {66},

publisher = {Pleiades Publishing},

month = {feb},

url = {https://doi.org/10.3103/S002713141101007X},

number = {1},

pages = {43--46},

doi = {10.3103/S002713141101007X}

}

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Nemilova, M. Yu., et al. “Ionselective electrodes based on adamantylthiacalix[4]arenes for alkali cations determination.” Moscow University Chemistry Bulletin, vol. 66, no. 1, Feb. 2011, pp. 43-46. https://doi.org/10.3103/S002713141101007X.