Cobalt(II) porphyrazine as an active component of iodide-selective electrodes
Publication type: Journal Article
Publication date: 2016-07-01
scimago Q4
wos Q4
SJR: 0.153
CiteScore: 1.1
Impact factor: 0.5
ISSN: 00271314, 19350260
General Chemistry
Abstract
Cobalt(II) porphyrazine is synthesized and studied as an active component of a polyvinyl chloride plasticized membrane ion-selective electrodes (ISEs). It is established that regardless of their structure, ISEs are sensitive to iodide. The introduction to the ISE of an ionic additive, ionic liquid 1,3-dihexadecylimidazolium chloride, significantly improves the electrochemical characteristics: the slope of the electrode function reaches −(57 ± 1) mV/dec, cmin = 8.3 × 10–6 M. Solid-state screen-printed electrodes the surfaces of which are modified by a 1: 4 mixture of cobalt(II) porphyrazine and ionic liquid 1,3-dihexadecylimidazolium chloride demonstrate satisfactory electrochemical characteristics: the slope of the electrode function is −(56 ± 4) mV/dec and cmin = 2.5 × 10–5 M. The potentiometric selectivity of the ISEs for iodide is studied. It is found that the effect of lipophilic interfering ions is significantly lower for solid state ISEs than for plasticized membrane electrodes.
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Otkidach K. N. et al. Cobalt(II) porphyrazine as an active component of iodide-selective electrodes // Moscow University Chemistry Bulletin. 2016. Vol. 71. No. 4. pp. 270-276.
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Otkidach K. N., Shvedene N. V., Tarakanov P. A., Tomilova L. G., Pletnev I. V. Cobalt(II) porphyrazine as an active component of iodide-selective electrodes // Moscow University Chemistry Bulletin. 2016. Vol. 71. No. 4. pp. 270-276.
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TY - JOUR
DO - 10.3103/S0027131416040064
UR - http://link.springer.com/10.3103/S0027131416040064
TI - Cobalt(II) porphyrazine as an active component of iodide-selective electrodes
T2 - Moscow University Chemistry Bulletin
AU - Otkidach, K N
AU - Shvedene, N V
AU - Tarakanov, P A
AU - Tomilova, L. G.
AU - Pletnev, I V
PY - 2016
DA - 2016/07/01
PB - Allerton Press
SP - 270-276
IS - 4
VL - 71
SN - 0027-1314
SN - 1935-0260
ER -
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@article{2016_Otkidach,
author = {K N Otkidach and N V Shvedene and P A Tarakanov and L. G. Tomilova and I V Pletnev},
title = {Cobalt(II) porphyrazine as an active component of iodide-selective electrodes},
journal = {Moscow University Chemistry Bulletin},
year = {2016},
volume = {71},
publisher = {Allerton Press},
month = {jul},
url = {http://link.springer.com/10.3103/S0027131416040064},
number = {4},
pages = {270--276},
doi = {10.3103/S0027131416040064}
}
Cite this
MLA
Copy
Otkidach, K. N., et al. “Cobalt(II) porphyrazine as an active component of iodide-selective electrodes.” Moscow University Chemistry Bulletin, vol. 71, no. 4, Jul. 2016, pp. 270-276. http://link.springer.com/10.3103/S0027131416040064.
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