Features of the Reaction of Ortho-Carboranyl Lithium with 3,6-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine
Publication type: Journal Article
Publication date: 2024-11-13
SJR: —
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ISSN: 0044460X
Abstract
The action of in situ generated ortho-carboranyl lithium on 3,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine leads to the formation of bis(ortho-carboranyl)diformylhydrazide as a product of the opening of the 1,2,4,5-tetrazine ring with the release of a nitrogen molecule, while the expected products of ipso-substitution of the pyrazole fragment were not detected. The structure of the obtained symmetrical bis(ortho-carboranyl)diformylhydrazide was established based on NMR spectroscopy, mass spectrometry and single crystal X-ray structural analysis.
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Moseev T. D. et al. Features of the Reaction of Ortho-Carboranyl Lithium with 3,6-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine // Журнал Общей Химии. 2024. Vol. 94. No. 6. pp. 705-711.
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Moseev T. D., Smyshlyaeva L. A., Kopchuk D. S., Ishmetova R. I., Slepukhin P. A., Rybakova A. V., Rusinov G., Zyryanov G. V., Varaksin M. V., Charushin V. N., Chupakhin O. Features of the Reaction of Ortho-Carboranyl Lithium with 3,6-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine // Журнал Общей Химии. 2024. Vol. 94. No. 6. pp. 705-711.
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TY - JOUR
DO - 10.31857/s0044460x24060048
UR - https://journals.rcsi.science/0044-460X/article/view/269851
TI - Features of the Reaction of Ortho-Carboranyl Lithium with 3,6-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine
T2 - Журнал Общей Химии
AU - Moseev, T D
AU - Smyshlyaeva, L. A.
AU - Kopchuk, D S
AU - Ishmetova, R I
AU - Slepukhin, P A
AU - Rybakova, A V
AU - Rusinov, G.L.
AU - Zyryanov, G V
AU - Varaksin, M V
AU - Charushin, V. N.
AU - Chupakhin, O.N.
PY - 2024
DA - 2024/11/13
PB - The Russian Academy of Sciences
SP - 705-711
IS - 6
VL - 94
SN - 0044-460X
ER -
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BibTex (up to 50 authors)
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@article{2024_Moseev,
author = {T D Moseev and L. A. Smyshlyaeva and D S Kopchuk and R I Ishmetova and P A Slepukhin and A V Rybakova and G.L. Rusinov and G V Zyryanov and M V Varaksin and V. N. Charushin and O.N. Chupakhin},
title = {Features of the Reaction of Ortho-Carboranyl Lithium with 3,6-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine},
journal = {Журнал Общей Химии},
year = {2024},
volume = {94},
publisher = {The Russian Academy of Sciences},
month = {nov},
url = {https://journals.rcsi.science/0044-460X/article/view/269851},
number = {6},
pages = {705--711},
doi = {10.31857/s0044460x24060048}
}
Cite this
MLA
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Moseev, T. D., et al. “Features of the Reaction of Ortho-Carboranyl Lithium with 3,6-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine.” Журнал Общей Химии, vol. 94, no. 6, Nov. 2024, pp. 705-711. https://journals.rcsi.science/0044-460X/article/view/269851.