Open Access
Frontiers in Chemistry, volume 10
Synthesis and Modification of Tetrahedron Li10.35Si1.35P1.65S12via Elemental Doping for All-Solid-State Lithium Batteries
1
College of Chemistry and Environmental Engineering, China
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2
Walker Department of Mechanical Engineering, United States
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Publication type: Journal Article
Publication date: 2022-03-22
Journal:
Frontiers in Chemistry
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 5.5
ISSN: 22962646, 22962646
General Chemistry
Abstract
Solid-state electrolyte (SSE), as the core component of solid-state batteries, plays a critical role in the performance of the batteries. Currently, the development of SSE is still hindered by its high price, low ionic conductivity, and poor interface stability. In this work, we report the tailored synthesis of a high ionic conductive and low cost sulfide SSE for all-solid-state lithium batteries. The Li10.35Si1.35P1.65S12 with favorable tetragonal structure was synthesis by increasing the concentration of Si4+, which shows an ionic conductivity of 4.28 × 10−3 S cm−1 and a wide electrochemical stability window of up to 5 V. By further modifying the composition of the electrolyte via ionic doping, the ionic conductivity of Li10.35Si1.35P1.65S12 can be further enhanced. Among them, the 1% Co4+-doped Li10.35Si1.35P1.65S12 shows the highest ionic conductivity of 6.91 × 10−3 S cm−1, 40% higher than the undoped one. This can be attributed to the broadened MS4− tetrahedrons and increased Li+ concentration. As a demonstration, an all-solid-state Li metal battery was assembled using TiS2 as the cathode and 1% Co4+-doped Li10.35Si1.35P1.65S12 as the electrolyte, showing capacity retention of 72% at the 110th cycle. This strategy is simple and can be easily extended for the construction of other high-performance sulfide SSEs.
Top-30
Citations by journals
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Energy Technology
1 publication, 16.67%
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Energy Storage Materials
1 publication, 16.67%
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Materials Today Sustainability
1 publication, 16.67%
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Nano Energy
1 publication, 16.67%
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Progress in Materials Science
1 publication, 16.67%
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Russian Chemical Reviews
1 publication, 16.67%
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1
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Citations by publishers
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4
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Elsevier
4 publications, 66.67%
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Wiley
1 publication, 16.67%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 16.67%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Lin Y. et al. Synthesis and Modification of Tetrahedron Li10.35Si1.35P1.65S12via Elemental Doping for All-Solid-State Lithium Batteries // Frontiers in Chemistry. 2022. Vol. 10.
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Lin Y., Chen J., Yan J., Yanhua Z., Lu H., Zhao C. Synthesis and Modification of Tetrahedron Li10.35Si1.35P1.65S12via Elemental Doping for All-Solid-State Lithium Batteries // Frontiers in Chemistry. 2022. Vol. 10.
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TY - JOUR
DO - 10.3389/fchem.2022.851264
UR - https://doi.org/10.3389/fchem.2022.851264
TI - Synthesis and Modification of Tetrahedron Li10.35Si1.35P1.65S12via Elemental Doping for All-Solid-State Lithium Batteries
T2 - Frontiers in Chemistry
AU - Lin, Yuanzhong
AU - Chen, Jian
AU - Yan, Jiawei
AU - Yanhua, Zhuang
AU - Lu, Hengyi
AU - Zhao, Chenyang
PY - 2022
DA - 2022/03/22 00:00:00
PB - Frontiers Media S.A.
VL - 10
SN - 2296-2646
SN - 2296-2646
ER -
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@article{2022_Lin,
author = {Yuanzhong Lin and Jian Chen and Jiawei Yan and Zhuang Yanhua and Hengyi Lu and Chenyang Zhao},
title = {Synthesis and Modification of Tetrahedron Li10.35Si1.35P1.65S12via Elemental Doping for All-Solid-State Lithium Batteries},
journal = {Frontiers in Chemistry},
year = {2022},
volume = {10},
publisher = {Frontiers Media S.A.},
month = {mar},
url = {https://doi.org/10.3389/fchem.2022.851264},
doi = {10.3389/fchem.2022.851264}
}