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Thiol-Epoxy Click Chemistry: The Synthesis of Vicinal Amino Alcohols Containing a 1,2,4-Triazole Ring
Artyom V. Petrosyan
1
,
Astghik A. Shahkhatuni
2
,
Andranik M. Davinyan
2
,
Karine S. Avetisyan
1
,
Tariel V Ghochikyan
1
,
Melanya A Samvelyan
1
,
Armen S Galstyan
1
Publication type: Journal Article
Publication date: 2025-04-01
Abstract
As examples of “Click Chemistry”, the reaction of 1-(oxiran-2-ylmethyl)piperidine with several 1,2,4-triazoles derivatives was studied. As a result, the reaction shows that the oxirane ring opens regiospecifically, according to Krasusky’s rule, without using a catalyst. The basic nitrogen present in 1-(oxiran-2-ylmethyl)piperidine has a catalytic (anchimer) effect.
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Petrosyan A. V. et al. Thiol-Epoxy Click Chemistry: The Synthesis of Vicinal Amino Alcohols Containing a 1,2,4-Triazole Ring // Chemistry. 2025. Vol. 7. No. 2. p. 53.
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Petrosyan A. V., Shahkhatuni A. A., Davinyan A. M., Avetisyan K. S., Ghochikyan T. V., Samvelyan M. A., Nenajdenko V. G., Galstyan A. S. Thiol-Epoxy Click Chemistry: The Synthesis of Vicinal Amino Alcohols Containing a 1,2,4-Triazole Ring // Chemistry. 2025. Vol. 7. No. 2. p. 53.
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TY - JOUR
DO - 10.3390/chemistry7020053
UR - https://www.mdpi.com/2624-8549/7/2/53
TI - Thiol-Epoxy Click Chemistry: The Synthesis of Vicinal Amino Alcohols Containing a 1,2,4-Triazole Ring
T2 - Chemistry
AU - Petrosyan, Artyom V.
AU - Shahkhatuni, Astghik A.
AU - Davinyan, Andranik M.
AU - Avetisyan, Karine S.
AU - Ghochikyan, Tariel V
AU - Samvelyan, Melanya A
AU - Nenajdenko, Valentine G.
AU - Galstyan, Armen S
PY - 2025
DA - 2025/04/01
PB - MDPI
SP - 53
IS - 2
VL - 7
SN - 2624-8549
ER -
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@article{2025_Petrosyan,
author = {Artyom V. Petrosyan and Astghik A. Shahkhatuni and Andranik M. Davinyan and Karine S. Avetisyan and Tariel V Ghochikyan and Melanya A Samvelyan and Valentine G. Nenajdenko and Armen S Galstyan},
title = {Thiol-Epoxy Click Chemistry: The Synthesis of Vicinal Amino Alcohols Containing a 1,2,4-Triazole Ring},
journal = {Chemistry},
year = {2025},
volume = {7},
publisher = {MDPI},
month = {apr},
url = {https://www.mdpi.com/2624-8549/7/2/53},
number = {2},
pages = {53},
doi = {10.3390/chemistry7020053}
}
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Petrosyan, Artyom V., et al. “Thiol-Epoxy Click Chemistry: The Synthesis of Vicinal Amino Alcohols Containing a 1,2,4-Triazole Ring.” Chemistry, vol. 7, no. 2, Apr. 2025, p. 53. https://www.mdpi.com/2624-8549/7/2/53.
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