Open Access
Crystals, volume 10, issue 11, pages 1016
The Na2−nHn[Zr(Si2O7)]∙mH2O Minerals and Related Compounds (n = 0–0.5; m = 0.1): Structure Refinement, Framework Topology, and Possible Na+-Ion Migration Paths
Kabanova Natalya A
1, 2
,
Panikorovskii T. L.
1, 3
,
Vlasenko Natalya S
4
,
Yakovenchuk Victor N.
5
,
Aksenov S. M.
1
,
Krivovichev Sergey V.
3, 6
Publication type: Journal Article
Publication date: 2020-11-09
Inorganic Chemistry
General Chemical Engineering
Condensed Matter Physics
General Materials Science
Abstract
The Na2−nHn[Zr(Si2O7)]∙mH2O family of minerals and related compounds (n = 0–0.5; m = 0.1) consist of keldyshite, Na3H[Zr2(Si2O7)2], and parakeldyshite, Na2[Zr(Si2O7)], and synthetic Na2[Zr(Si2O7)]∙H2O. The crystal structures of these materials are based upon microporous heteropolyhedral frameworks formed by linkage of Si2O7 groups and ZrO6 octahedra with internal channels occupied by Na+ cations and H2O molecules. The members of the family have been studied by the combination of theoretical (geometrical–topological analysis, Voronoi migration map calculation, structural complexity calculation), and empirical methods (single-crystal X-ray diffraction, microprobe analysis, and Raman spectroscopy for parakeldyshite). It was found that keldyshite and parakeldyshite have the same fsh topology, while Na2ZrSi2O7∙H2O is different and has the xat topology. The microporous heteropolyhedral frameworks in these materials have a 2-D system of channels suitable for the Na+-ion migration. The crystal structure of keldyshite can be derived from that of parakeldyshite by the Na+ + O2− ↔ OH− + □ substitution mechanism, widespread in the postcrystallization processes in hyperagpaitic rocks.
Citations by journals
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1
2
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Journal of Structural Chemistry
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Journal of Structural Chemistry
2 publications, 33.33%
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Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
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Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
1 publication, 16.67%
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European Journal of Mineralogy
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European Journal of Mineralogy
1 publication, 16.67%
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Mineralogical Magazine
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Mineralogical Magazine
1 publication, 16.67%
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Minerals
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Minerals
1 publication, 16.67%
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1
2
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Citations by publishers
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1
2
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Pleiades Publishing
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Pleiades Publishing
2 publications, 33.33%
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International Union of Crystallography (IUCr)
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International Union of Crystallography (IUCr)
1 publication, 16.67%
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Copernicus
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Copernicus
1 publication, 16.67%
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Mineralogical Society
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Mineralogical Society
1 publication, 16.67%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 16.67%
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1
2
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Kabanova N. A. et al. The Na2−nHn[Zr(Si2O7)]∙mH2O Minerals and Related Compounds (n = 0–0.5; m = 0.1): Structure Refinement, Framework Topology, and Possible Na+-Ion Migration Paths // Crystals. 2020. Vol. 10. No. 11. p. 1016.
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Kabanova N. A., Panikorovskii T. L., Shilovskikh V. V., Vlasenko N. S., Yakovenchuk V. N., Aksenov S. M., Bocharov V. M., Krivovichev S. V. The Na2−nHn[Zr(Si2O7)]∙mH2O Minerals and Related Compounds (n = 0–0.5; m = 0.1): Structure Refinement, Framework Topology, and Possible Na+-Ion Migration Paths // Crystals. 2020. Vol. 10. No. 11. p. 1016.
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TY - JOUR
DO - 10.3390/cryst10111016
UR - https://doi.org/10.3390%2Fcryst10111016
TI - The Na2−nHn[Zr(Si2O7)]∙mH2O Minerals and Related Compounds (n = 0–0.5; m = 0.1): Structure Refinement, Framework Topology, and Possible Na+-Ion Migration Paths
T2 - Crystals
AU - Kabanova, Natalya A
AU - Vlasenko, Natalya S
AU - Yakovenchuk, Victor N.
AU - Krivovichev, Sergey V.
AU - Panikorovskii, T. L.
AU - Shilovskikh, Vladimir V.
AU - Aksenov, S. M.
AU - Bocharov, Vladimir M.
PY - 2020
DA - 2020/11/09 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 1016
IS - 11
VL - 10
SN - 2073-4352
SN - 0172-5076
ER -
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@article{2020_Kabanova,
author = {Natalya A Kabanova and Natalya S Vlasenko and Victor N. Yakovenchuk and Sergey V. Krivovichev and T. L. Panikorovskii and Vladimir V. Shilovskikh and S. M. Aksenov and Vladimir M. Bocharov},
title = {The Na2−nHn[Zr(Si2O7)]∙mH2O Minerals and Related Compounds (n = 0–0.5; m = 0.1): Structure Refinement, Framework Topology, and Possible Na+-Ion Migration Paths},
journal = {Crystals},
year = {2020},
volume = {10},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {nov},
url = {https://doi.org/10.3390%2Fcryst10111016},
number = {11},
pages = {1016},
doi = {10.3390/cryst10111016}
}
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Kabanova, Natalya A., et al. “The Na2−nHn[Zr(Si2O7)]∙mH2O Minerals and Related Compounds (n = 0–0.5; m = 0.1): Structure Refinement, Framework Topology, and Possible Na+-Ion Migration Paths.” Crystals, vol. 10, no. 11, Nov. 2020, p. 1016. https://doi.org/10.3390%2Fcryst10111016.