Open Access
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Energies, volume 16, issue 23, pages 7713

Evaluation of Pt-Co Nano-Catalyzed Membranes for Polymer Electrolyte Membrane Fuel Cell Applications

Sethu Sundar Pethaiah 1
Arunkumar Jayakumar 1
Kalyani Palanichamy 2
1
 
School of Engineering and Technology, St. Peter’s Institute of Higher Education and Research, Chennai 600054, India
Publication typeJournal Article
Publication date2023-11-22
Journal: Energies
scimago Q1
SJR0.651
CiteScore6.2
Impact factor3
ISSN19961073
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Building and Construction
Control and Optimization
Engineering (miscellaneous)
Energy (miscellaneous)
Abstract

The membrane electrode assembly (MEA) encompassing the polymer electrolyte membrane (PEM) and catalyst layers are the key components in Polymer Electrolyte Membrane Fuel Cells (PEMFCs). The cost of the PEMFC stacks has been limiting its commercialization due to the inflated price of conventional platinum (Pt)-based catalysts. As a consequence, the authors of this paper focus on developing novel bi-metallic (Pt-Co) nano-alloy-catalyzed MEAs using the non-equilibrium impregnation–reduction (NEIR) approach with an aim to reduce the Pt content, and hence, the cost. Herein, the MEAs are fabricated on a Nafion® membrane with a 0.4 mgPtcm−2 Pt:Co electrocatalyst loading at three atomic ratios, viz., 90:10, 70:30, and 50:50. The High Resolution-Scanning Electron Microscopic (HR-SEM) characterization of the MEAs show a favorable surface morphology with a uniform distribution of Pt-Co alloy particles with an average size of about 15–25 µm. Under standard fuel cell test conditions, an MEA with a 50:50 atomic ratio of Pt:Co exhibited a peak power density of 0.879 Wcm−2 for H2/O2 and 0.727 Wcm−2 for H2/air systems. The X-ray diffractometry (XRD), SEM, EDX, Cyclic Voltammetry (CV), impedance, and polarization studies validate that Pt:Co can be a potential affordable alternative to high-cost Pt. Additionally, a high degree of stability in the fuel cell performance was also demonstrated with Pt50:Co50.

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