Open Access
International Journal of Molecular Sciences, volume 21, issue 15, pages 5517
Selectivity of Transport Processes in Ion-Exchange Membranes: Relationship with the Structure and Methods for Its Improvement
Publication type: Journal Article
Publication date: 2020-08-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.6
ISSN: 16616596, 14220067
PubMed ID:
32752236
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Computer Science Applications
Spectroscopy
Molecular Biology
General Medicine
Abstract
Nowadays, ion-exchange membranes have numerous applications in water desalination, electrolysis, chemistry, food, health, energy, environment and other fields. All of these applications require high selectivity of ion transfer, i.e., high membrane permselectivity. The transport properties of ion-exchange membranes are determined by their structure, composition and preparation method. For various applications, the selectivity of transfer processes can be characterized by different parameters, for example, by the transport number of counterions (permselectivity in electrodialysis) or by the ratio of ionic conductivity to the permeability of some gases (crossover in fuel cells). However, in most cases there is a correlation: the higher the flux density of the target component through the membrane, the lower the selectivity of the process. This correlation has two aspects: first, it follows from the membrane material properties, often expressed as the trade-off between membrane permeability and permselectivity; and, second, it is due to the concentration polarization phenomenon, which increases with an increase in the applied driving force. In this review, both aspects are considered. Recent research and progress in the membrane selectivity improvement, mainly including a number of approaches as crosslinking, nanoparticle doping, surface modification, and the use of special synthetic methods (e.g., synthesis of grafted membranes or membranes with a fairly rigid three-dimensional matrix) are summarized. These approaches are promising for the ion-exchange membranes synthesis for electrodialysis, alternative energy, and the valuable component extraction from natural or waste-water. Perspectives on future development in this research field are also discussed.
Citations by journals
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14
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Polymers
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3 publications, 3%
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2 publications, 2%
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Mendeleev Communications
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2 publications, 2%
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2 publications, 2%
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1 publication, 1%
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1 publication, 1%
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1 publication, 1%
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Journal of Applied Polymer Science
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Journal of Applied Polymer Science
1 publication, 1%
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Colloid and Polymer Science
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1 publication, 1%
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Inorganic Materials
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1 publication, 1%
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Solid State Ionics
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Solid State Ionics
1 publication, 1%
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Sustainability
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Sustainability
1 publication, 1%
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Nature Nanotechnology
1 publication, 1%
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Chinese Chemical Letters
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Chinese Chemical Letters
1 publication, 1%
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Journal of Environmental Chemical Engineering
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Journal of Environmental Chemical Engineering
1 publication, 1%
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Sustainable Energy Technologies and Assessments
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Sustainable Energy Technologies and Assessments
1 publication, 1%
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Journal of Physics: Conference Series
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Journal of Physics: Conference Series
1 publication, 1%
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IOP Conference Series: Earth and Environmental Science
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IOP Conference Series: Earth and Environmental Science
1 publication, 1%
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ACS Applied Engineering Materials
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ACS Applied Engineering Materials
1 publication, 1%
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Journal of Physical Chemistry C
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Journal of Physical Chemistry C
1 publication, 1%
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14
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Citations by publishers
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5
10
15
20
25
30
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Elsevier
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Elsevier
29 publications, 29%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
23 publications, 23%
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Pleiades Publishing
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Pleiades Publishing
17 publications, 17%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
12 publications, 12%
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Wiley
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Wiley
5 publications, 5%
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Springer Nature
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Springer Nature
3 publications, 3%
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IOP Publishing
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IOP Publishing
2 publications, 2%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 2%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1%
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Taylor & Francis
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Taylor & Francis
1 publication, 1%
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5
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25
30
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Stenina I. et al. Selectivity of Transport Processes in Ion-Exchange Membranes: Relationship with the Structure and Methods for Its Improvement // International Journal of Molecular Sciences. 2020. Vol. 21. No. 15. p. 5517.
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Stenina I., Golubenko D., Nikonenko V. V., Yaroslavtsev A. B. Selectivity of Transport Processes in Ion-Exchange Membranes: Relationship with the Structure and Methods for Its Improvement // International Journal of Molecular Sciences. 2020. Vol. 21. No. 15. p. 5517.
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TY - JOUR
DO - 10.3390/ijms21155517
UR - https://doi.org/10.3390%2Fijms21155517
TI - Selectivity of Transport Processes in Ion-Exchange Membranes: Relationship with the Structure and Methods for Its Improvement
T2 - International Journal of Molecular Sciences
AU - Stenina, Irina
AU - Golubenko, Daniel
AU - Nikonenko, V. V.
AU - Yaroslavtsev, A. B.
PY - 2020
DA - 2020/08/01 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 5517
IS - 15
VL - 21
PMID - 32752236
SN - 1661-6596
SN - 1422-0067
ER -
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@article{2020_Stenina,
author = {Irina Stenina and Daniel Golubenko and V. V. Nikonenko and A. B. Yaroslavtsev},
title = {Selectivity of Transport Processes in Ion-Exchange Membranes: Relationship with the Structure and Methods for Its Improvement},
journal = {International Journal of Molecular Sciences},
year = {2020},
volume = {21},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {aug},
url = {https://doi.org/10.3390%2Fijms21155517},
number = {15},
pages = {5517},
doi = {10.3390/ijms21155517}
}
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MLA
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Stenina, Irina, et al. “Selectivity of Transport Processes in Ion-Exchange Membranes: Relationship with the Structure and Methods for Its Improvement.” International Journal of Molecular Sciences, vol. 21, no. 15, Aug. 2020, p. 5517. https://doi.org/10.3390%2Fijms21155517.