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(2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione)
Publication type: Journal Article
Publication date: 2024-01-24
DOI:
10.3390/m1764
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
In this work, the title compound was synthesized via the reaction of an aryl-substituted pyrazole with potassium tetrachloroplatinate, followed by the reaction of the postulated intermediate chloro-bridged dimer with a pyrazole-containing 1,3-diketonate ligand. The structure of the synthesized complex was established by 1H, 13C NMR spectroscopy and mass spectrometry. According to UV-Vis spectrometry studies, the obtained complex exhibits green fluorescence with a maximum at 514 nm. Based on cyclic voltammetry studies, the HOMO, LUMO and band gap values were calculated.
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Vlasova T. S. et al. (2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione) // MolBank. 2024. Vol. 2024. No. 1. p. M1764.
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Vlasova T. S., Romanova Y. E., Taydakov I. V., Paveliev S. A. (2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione) // MolBank. 2024. Vol. 2024. No. 1. p. M1764.
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TY - JOUR
DO - 10.3390/m1764
UR - https://doi.org/10.3390/m1764
TI - (2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione)
T2 - MolBank
AU - Vlasova, Tatiana S
AU - Romanova, Yulia E
AU - Taydakov, Ilya V.
AU - Paveliev, Stanislav A
PY - 2024
DA - 2024/01/24
PB - MDPI
SP - M1764
IS - 1
VL - 2024
SN - 1422-8599
ER -
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@article{2024_Vlasova,
author = {Tatiana S Vlasova and Yulia E Romanova and Ilya V. Taydakov and Stanislav A Paveliev},
title = {(2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione)},
journal = {MolBank},
year = {2024},
volume = {2024},
publisher = {MDPI},
month = {jan},
url = {https://doi.org/10.3390/m1764},
number = {1},
pages = {M1764},
doi = {10.3390/m1764}
}
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Vlasova, Tatiana S., et al. “(2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione).” MolBank, vol. 2024, no. 1, Jan. 2024, p. M1764. https://doi.org/10.3390/m1764.