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,  volume 2024 ,  issue 3 ,  pages M1846

A (2-(Pyrrolidin-1-yl)ethan-1-olate)(1-oxo-3-phenyl-1,4-dihydronaphthalen-2-olate) μ-Oxo-Bridged Dicopper(II) Dimeric Complex

Rylan Artis 1
, 
Clifford W. Padgett 1
, 
Kennedy Musso 1
, 
Nathaniel Shank 1
, 
ALLISON MARKS 1
, 
Brandon Quillian 1
1
 
Publication type: Journal Article
Publication date: 2024-07-05
MDPI
scimago Q4
wos Q4
SJR: 0.142
CiteScore: 0.9
Impact factor: 0.4
ISSN: 14228599
Abstract

The reaction of 2-(1H-pyrrol-1-yl)ethanol with 3-hydroxyflavone in the presence of copper(II) bromide yielded a dimeric copper(II) complex, [μ-O-(κ2-O,O-flav)(κ2-N,O-2PEO)Cu]2 (1) (flav = 3-hydroxyflavonolate; 2PEO = 2-(1H-pyrrol-1-yl)ethanolate) with both the flav and 2PEO ligands bound to the copper(II) atom in a κ2-bonding mode. The dimer is held electrostatically by bridging oxygen atoms between two copper atoms. Complex 1 was characterized by single-crystal X-ray diffraction, infrared, and UV-Vis spectroscopy, elemental analysis, and melting point determination. The complex crystallizes in the monoclinic space group P21/n (14) with cell values of a = 11.85340(10) Å, b = 8.51480(10) Å, c = 23.8453(2) Å; β = 99.3920(10)°.

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Artis R. et al. A (2-(Pyrrolidin-1-yl)ethan-1-olate)(1-oxo-3-phenyl-1,4-dihydronaphthalen-2-olate) μ-Oxo-Bridged Dicopper(II) Dimeric Complex // MolBank. 2024. Vol. 2024. No. 3. p. M1846.
GOST all authors (up to 50) Copy
Artis R., Padgett C. W., Musso K., Shank N., MARKS A., Quillian B. A (2-(Pyrrolidin-1-yl)ethan-1-olate)(1-oxo-3-phenyl-1,4-dihydronaphthalen-2-olate) μ-Oxo-Bridged Dicopper(II) Dimeric Complex // MolBank. 2024. Vol. 2024. No. 3. p. M1846.
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TY - JOUR
DO - 10.3390/m1846
UR - https://www.mdpi.com/1422-8599/2024/3/M1846
TI - A (2-(Pyrrolidin-1-yl)ethan-1-olate)(1-oxo-3-phenyl-1,4-dihydronaphthalen-2-olate) μ-Oxo-Bridged Dicopper(II) Dimeric Complex
T2 - MolBank
AU - Artis, Rylan
AU - Padgett, Clifford W.
AU - Musso, Kennedy
AU - Shank, Nathaniel
AU - MARKS, ALLISON
AU - Quillian, Brandon
PY - 2024
DA - 2024/07/05
PB - MDPI
SP - M1846
IS - 3
VL - 2024
SN - 1422-8599
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Artis,
author = {Rylan Artis and Clifford W. Padgett and Kennedy Musso and Nathaniel Shank and ALLISON MARKS and Brandon Quillian},
title = {A (2-(Pyrrolidin-1-yl)ethan-1-olate)(1-oxo-3-phenyl-1,4-dihydronaphthalen-2-olate) μ-Oxo-Bridged Dicopper(II) Dimeric Complex},
journal = {MolBank},
year = {2024},
volume = {2024},
publisher = {MDPI},
month = {jul},
url = {https://www.mdpi.com/1422-8599/2024/3/M1846},
number = {3},
pages = {M1846},
doi = {10.3390/m1846}
}
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Artis, Rylan, et al. “A (2-(Pyrrolidin-1-yl)ethan-1-olate)(1-oxo-3-phenyl-1,4-dihydronaphthalen-2-olate) μ-Oxo-Bridged Dicopper(II) Dimeric Complex.” MolBank, vol. 2024, no. 3, Jul. 2024, p. M1846. https://www.mdpi.com/1422-8599/2024/3/M1846.