Open Access
Minerals, volume 9, issue 8, pages 492
Dritsite, Li2Al4(OH)12Cl2·3H2O, a New Gibbsite-Based Hydrotalcite Supergroup Mineral
Zhitova E. S.
1, 2
,
Pekov Igor V.
3
,
Chaikovskiy Ilya I.
4
,
Chirkova Elena P
4
,
Yapaskurt Vasiliy O.
3
,
Bychkova Yana V.
3
,
Belakovskiy Dmitry I.
5
,
Chukanov Nikita V.
6
,
Zubkova Natalia V.
3
,
Krivovichev Sergey V.
1, 7
,
Bocharov Vladimir N.
8
7
Publication type: Journal Article
Publication date: 2019-08-17
Geotechnical Engineering and Engineering Geology
Geology
Abstract
Dritsite, ideally Li2Al4(OH)12Cl2·3H2O, is a new hydrotalcite supergroup mineral formed as a result of diagenesis in the halite−carnallite rock of the Verkhnekamskoe salt deposit, Perm Krai, Russia. Dritsite forms single lamellar or tabular hexagonal crystals up to 0.25 mm across. The mineral is transparent and colourless, with perfect cleavage on {001}. The chemical composition of dritsite (wt. %; by combination of electron microprobe and ICP−MS; H2O calculated by structure refinement) is: Li2O 6.6, Al2O3 45.42, SiO2 0.11, Cl 14.33, SO3 0.21, H2Ocalc. 34.86, O = Cl − 3.24, total 98.29. The empirical formula based on Li + Al + Si = 6 apfu (atom per formula unit) is Li1.99Al4.00Si0.01[(OH)12.19Cl1.82(SO4)0.01]Σ14.02·2.60(H2O). The Raman spectroscopic data indicate the presence of O–H bonding in the mineral, whereas CO32– groups are absent. The crystal structure has been refined in the space group P63/mcm, a = 5.0960(3), c = 15.3578(13) Å, and V = 345.4(5) Å3, to R1 = 0.088 using single-crystal data. The strongest lines of the powder X-ray diffraction pattern (d, Å (I, %) (hkl)) are: 7.68 (100) (002), 4.422 (61) (010), 3.832 (99) (004, 012), 2.561 (30) (006), 2.283 (25) (113), and 1.445 (26) (032). Dritsite was found as 2H polytype, which is isotypic with synthetic material and shows strong similarity to chlormagalumite-2H. The mineral is named in honour of the Russian crystallographer and mineralogist Prof. Victor Anatol`evich Drits.
Citations by journals
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1
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Mineralogical Magazine
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2 publications, 14.29%
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1 publication, 7.14%
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Journal of Environmental Chemical Engineering
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1 publication, 7.14%
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Chemistry of Materials
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1 publication, 7.14%
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1 publication, 7.14%
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Annual Reports on NMR Spectroscopy
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Annual Reports on NMR Spectroscopy
1 publication, 7.14%
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Applied Clay Science
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Applied Clay Science
1 publication, 7.14%
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Nano Research
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1 publication, 7.14%
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1 publication, 7.14%
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1
2
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Citations by publishers
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1
2
3
4
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Multidisciplinary Digital Publishing Institute (MDPI)
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4 publications, 28.57%
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Elsevier
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3 publications, 21.43%
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Mineralogical Society
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2 publications, 14.29%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
2 publications, 14.29%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 7.14%
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Springer Nature
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Springer Nature
1 publication, 7.14%
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3
4
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zhitova E. S. et al. Dritsite, Li2Al4(OH)12Cl2·3H2O, a New Gibbsite-Based Hydrotalcite Supergroup Mineral // Minerals. 2019. Vol. 9. No. 8. p. 492.
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Zhitova E. S., Pekov I. V., Chaikovskiy I. I., Chirkova E. P., Yapaskurt V. O., Bychkova Y. V., Belakovskiy D. I., Chukanov N. V., Zubkova N. V., Krivovichev S. V., Bocharov V. N. Dritsite, Li2Al4(OH)12Cl2·3H2O, a New Gibbsite-Based Hydrotalcite Supergroup Mineral // Minerals. 2019. Vol. 9. No. 8. p. 492.
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TY - JOUR
DO - 10.3390/min9080492
UR - https://doi.org/10.3390%2Fmin9080492
TI - Dritsite, Li2Al4(OH)12Cl2·3H2O, a New Gibbsite-Based Hydrotalcite Supergroup Mineral
T2 - Minerals
AU - Pekov, Igor V.
AU - Chaikovskiy, Ilya I.
AU - Chirkova, Elena P
AU - Yapaskurt, Vasiliy O.
AU - Bychkova, Yana V.
AU - Belakovskiy, Dmitry I.
AU - Chukanov, Nikita V.
AU - Zubkova, Natalia V.
AU - Krivovichev, Sergey V.
AU - Bocharov, Vladimir N.
AU - Zhitova, E. S.
PY - 2019
DA - 2019/08/17 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 492
IS - 8
VL - 9
SN - 2075-163X
ER -
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@article{2019_Zhitova,
author = {Igor V. Pekov and Ilya I. Chaikovskiy and Elena P Chirkova and Vasiliy O. Yapaskurt and Yana V. Bychkova and Dmitry I. Belakovskiy and Nikita V. Chukanov and Natalia V. Zubkova and Sergey V. Krivovichev and Vladimir N. Bocharov and E. S. Zhitova},
title = {Dritsite, Li2Al4(OH)12Cl2·3H2O, a New Gibbsite-Based Hydrotalcite Supergroup Mineral},
journal = {Minerals},
year = {2019},
volume = {9},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {aug},
url = {https://doi.org/10.3390%2Fmin9080492},
number = {8},
pages = {492},
doi = {10.3390/min9080492}
}
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Zhitova, E. S., et al. “Dritsite, Li2Al4(OH)12Cl2·3H2O, a New Gibbsite-Based Hydrotalcite Supergroup Mineral.” Minerals, vol. 9, no. 8, Aug. 2019, p. 492. https://doi.org/10.3390%2Fmin9080492.
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