Open Access
Molecules, volume 24, issue 13, pages 2476
Polymerization Assisted by Upconversion Nanoparticles under NIR Light
Demina Polina
1, 2
,
Arkharova Natalya
1
,
Asharchuk Ilya
1
,
Khaydukov Kirill
1
,
Karimov D. N.
1
,
Rocheva Vasilina
1
,
Nechaev Andrey
1, 3
,
Grigoriev Yuri
1
,
Generalova Alla
1, 2
,
Khaydukov Evgeny V.
1, 4, 5
4
Publication type: Journal Article
Publication date: 2019-07-05
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
Photopolymerization of nanocomposite materials using near infrared light is one of the unique technologies based on the luminescent properties of lanthanide-doped upconversion nanoparticles (UCNPs). We explored the UCNP-triggered radical polymerization both in oligomer bulk and on the nanoparticle surface in aqueous dispersion. Core/shell UCNPs NaYF4:Yb3+ and Tm3+/NaYF4 with emitting lines in the ultraviolet and blue regions were used to activate a photoinitiator. The study of the bulk photopolymerization in an initially homogeneous reaction mixture showed the UCNP redistribution due to gradient density occurring in the volume, which led to formation of UCNP superlattices and spheres “frozen” in a polymer matrix. We also developed a strategy of “grafting from” the surface, providing polymer shell growth directly on the nanoparticles. The photosensitization of the endogenous water-soluble photoinitiator riboflavin by the resonance energy transfer from UCNPs was demonstrated in the course of monomer glycidyl methacrylate polymerization followed by photocrosslinking with poly(ethylene glycol) diacrylate on the nanoparticle surface.
Citations by journals
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1
2
3
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European Polymer Journal
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European Polymer Journal
3 publications, 14.29%
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Nanomaterials
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Nanomaterials
1 publication, 4.76%
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Nature
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Nature
1 publication, 4.76%
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Materials Today Chemistry
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Materials Today Chemistry
1 publication, 4.76%
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Nano-Structures and Nano-Objects
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Nano-Structures and Nano-Objects
1 publication, 4.76%
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Laser Physics Letters
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Laser Physics Letters
1 publication, 4.76%
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Photochemistry and Photobiology
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Photochemistry and Photobiology
1 publication, 4.76%
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Chemical Record
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Chemical Record
1 publication, 4.76%
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ChemPhysChem
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ChemPhysChem
1 publication, 4.76%
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Macromolecular Chemistry and Physics
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Macromolecular Chemistry and Physics
1 publication, 4.76%
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Biomaterials Science
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Biomaterials Science
1 publication, 4.76%
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Nanotechnologies in Russia
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Nanotechnologies in Russia
1 publication, 4.76%
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Photonics Russia
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Photonics Russia, 1, 4.76%
Photonics Russia
1 publication, 4.76%
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Polymer Chemistry
|
Polymer Chemistry
1 publication, 4.76%
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ACS Photonics
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ACS Photonics
1 publication, 4.76%
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Biomacromolecules
|
Biomacromolecules
1 publication, 4.76%
|
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Applied Surface Science
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Applied Surface Science
1 publication, 4.76%
|
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Russian Chemical Reviews
|
Russian Chemical Reviews
1 publication, 4.76%
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1
2
3
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Citations by publishers
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1
2
3
4
5
6
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Elsevier
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Elsevier
6 publications, 28.57%
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Wiley
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Wiley
4 publications, 19.05%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 9.52%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
2 publications, 9.52%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 4.76%
|
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Springer Nature
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Springer Nature
1 publication, 4.76%
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IOP Publishing
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IOP Publishing
1 publication, 4.76%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 4.76%
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Technosphera JSC
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Technosphera JSC, 1, 4.76%
Technosphera JSC
1 publication, 4.76%
|
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 4.76%
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1
2
3
4
5
6
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Demina P. et al. Polymerization Assisted by Upconversion Nanoparticles under NIR Light // Molecules. 2019. Vol. 24. No. 13. p. 2476.
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Demina P., Arkharova N., Asharchuk I., Khaydukov K., Karimov D. N., Rocheva V., Nechaev A., Grigoriev Y., Generalova A., Khaydukov E. V. Polymerization Assisted by Upconversion Nanoparticles under NIR Light // Molecules. 2019. Vol. 24. No. 13. p. 2476.
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RIS
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TY - JOUR
DO - 10.3390/molecules24132476
UR - https://doi.org/10.3390%2Fmolecules24132476
TI - Polymerization Assisted by Upconversion Nanoparticles under NIR Light
T2 - Molecules
AU - Demina, Polina
AU - Arkharova, Natalya
AU - Asharchuk, Ilya
AU - Khaydukov, Kirill
AU - Rocheva, Vasilina
AU - Nechaev, Andrey
AU - Generalova, Alla
AU - Karimov, D. N.
AU - Grigoriev, Yuri
AU - Khaydukov, Evgeny V.
PY - 2019
DA - 2019/07/05 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 2476
IS - 13
VL - 24
SN - 1420-3049
ER -
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@article{2019_Demina,
author = {Polina Demina and Natalya Arkharova and Ilya Asharchuk and Kirill Khaydukov and Vasilina Rocheva and Andrey Nechaev and Alla Generalova and D. N. Karimov and Yuri Grigoriev and Evgeny V. Khaydukov},
title = {Polymerization Assisted by Upconversion Nanoparticles under NIR Light},
journal = {Molecules},
year = {2019},
volume = {24},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {jul},
url = {https://doi.org/10.3390%2Fmolecules24132476},
number = {13},
pages = {2476},
doi = {10.3390/molecules24132476}
}
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Demina, Polina, et al. “Polymerization Assisted by Upconversion Nanoparticles under NIR Light.” Molecules, vol. 24, no. 13, Jul. 2019, p. 2476. https://doi.org/10.3390%2Fmolecules24132476.
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