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Nanomaterials, volume 12, issue 19, pages 3314

Dual-Purpose Sensing Nanoprobe Based on Carbon Dots from o-Phenylenediamine: pH and Solvent Polarity Measurement

Publication typeJournal Article
Publication date2022-09-23
Journal: Nanomaterials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.3
ISSN20794991
PubMed ID:  36234443
General Chemical Engineering
General Materials Science
Abstract

Today, the development of nanomaterials with sensing properties attracts much scientific interest because of the demand for low-cost nontoxic colloidal nanoprobes with high sensitivity and selectivity for various biomedical and environment-related applications. Carbon dots (CDs) are promising candidates for these applications as they demonstrate unique optical properties with intense emissions, biocompatibility, and ease of fabrication. Herein, we developed synthesis protocols to obtain CDs based on o-phenylenediamine with a variety of optical responses depending on additional precursors and changes in the reaction media. The obtained CDs are N-doped (N,S-doped in case of thiourea addition) less than 10 nm spherical particles with emissions observed in the 300–600 nm spectral region depending on their chemical composition. These CDs may act simultaneously as absorptive/fluorescent sensing probes for solvent polarity with ∆S/∆ENT  up to 85, for ∆ENT from 0.099 to 1.0 and for pH values in the range of 3.0–8.0, thus opening an opportunity to check the pH in non-pure water or a mixture of solvents. Moreover, CDs preserve their optical properties when embedded in cellulose strips that can be used as sensing probes for fast and easy pH checks. We believe that the resulting dual-purpose sensing nano probes based on CDs will have high demand in various sensing applications.

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Vedernikova A. A. et al. Dual-Purpose Sensing Nanoprobe Based on Carbon Dots from o-Phenylenediamine: pH and Solvent Polarity Measurement // Nanomaterials. 2022. Vol. 12. No. 19. p. 3314.
GOST all authors (up to 50) Copy
Vedernikova A. A., Miruschenko M. D., Arefina I. A., Babaev A. A., Stepanidenko E. A., Cherevkov S. A., Spiridonov I. G., Danilov D. V., Koroleva A. V., Zhizhin E. V., Ushakova E. V. Dual-Purpose Sensing Nanoprobe Based on Carbon Dots from o-Phenylenediamine: pH and Solvent Polarity Measurement // Nanomaterials. 2022. Vol. 12. No. 19. p. 3314.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3390/nano12193314
UR - https://doi.org/10.3390%2Fnano12193314
TI - Dual-Purpose Sensing Nanoprobe Based on Carbon Dots from o-Phenylenediamine: pH and Solvent Polarity Measurement
T2 - Nanomaterials
AU - Vedernikova, Anna A.
AU - Arefina, Irina A.
AU - Babaev, Anton A.
AU - Spiridonov, Igor G.
AU - Koroleva, Aleksandra V.
AU - Miruschenko, Mikhail D.
AU - Stepanidenko, Evgeniia A.
AU - Cherevkov, Sergei A.
AU - Danilov, Denis V.
AU - Zhizhin, Evgeniy V.
AU - Ushakova, Elena V.
PY - 2022
DA - 2022/09/23 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 3314
IS - 19
VL - 12
PMID - 36234443
SN - 2079-4991
ER -
BibTex |
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BibTex Copy
@article{2022_Vedernikova,
author = {Anna A. Vedernikova and Irina A. Arefina and Anton A. Babaev and Igor G. Spiridonov and Aleksandra V. Koroleva and Mikhail D. Miruschenko and Evgeniia A. Stepanidenko and Sergei A. Cherevkov and Denis V. Danilov and Evgeniy V. Zhizhin and Elena V. Ushakova},
title = {Dual-Purpose Sensing Nanoprobe Based on Carbon Dots from o-Phenylenediamine: pH and Solvent Polarity Measurement},
journal = {Nanomaterials},
year = {2022},
volume = {12},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {sep},
url = {https://doi.org/10.3390%2Fnano12193314},
number = {19},
pages = {3314},
doi = {10.3390/nano12193314}
}
MLA
Cite this
MLA Copy
Vedernikova, Anna A., et al. “Dual-Purpose Sensing Nanoprobe Based on Carbon Dots from o-Phenylenediamine: pH and Solvent Polarity Measurement.” Nanomaterials, vol. 12, no. 19, Sep. 2022, p. 3314. https://doi.org/10.3390%2Fnano12193314.
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