Open Access
A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters
Maxim Temnikov
1
,
Maxim A Novikov
2
,
Mikhail I Buzin
1
,
Galina G Nikiforova
1
,
Yulia S Dyuzhikova
1
,
Ivan E. Ushakov
1
,
Olga I Shchegolikhina
1
,
Aziz M. Muzafarov
1, 3
Publication type: Journal Article
Publication date: 2021-12-18
PubMed ID:
34961003
General Chemistry
Polymers and Plastics
Abstract
A versatile equilibrium method for synthesizing ladder-like polyphenylsilsesquioxanes (L-PPSQs) with various molecular weights (from 4 to 500 kDa) in liquid ammonia was developed. The effect of diverse parameters, such as temperature, monomer concentration, reaction time, addition or removal of water from the reaction medium, on the polycondensation process was determined. The molecular weight characteristics and structure of the L-PPSQ elements obtained were determined by GPC, 1H, 29Si NMR, IR spectroscopy, viscometry, and PXRD methods. The physicochemical properties of L-PPSQs were determined by TGA and mechanical analyses.
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19
Total citations:
19
Citations from 2024:
9
(47%)
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GOST
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Ershova T. O. et al. A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters // Polymers. 2021. Vol. 13. No. 24. p. 4452.
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Ershova T. O., Anisimov A. A., Temnikov M., Novikov M. A., Buzin M. I., Nikiforova G. G., Dyuzhikova Y. S., Ushakov I. E., Shchegolikhina O. I., Muzafarov A. M. A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters // Polymers. 2021. Vol. 13. No. 24. p. 4452.
Cite this
RIS
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TY - JOUR
DO - 10.3390/polym13244452
UR - https://doi.org/10.3390/polym13244452
TI - A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters
T2 - Polymers
AU - Ershova, Tatyana O
AU - Anisimov, Anton A.
AU - Temnikov, Maxim
AU - Novikov, Maxim A
AU - Buzin, Mikhail I
AU - Nikiforova, Galina G
AU - Dyuzhikova, Yulia S
AU - Ushakov, Ivan E.
AU - Shchegolikhina, Olga I
AU - Muzafarov, Aziz M.
PY - 2021
DA - 2021/12/18
PB - MDPI
SP - 4452
IS - 24
VL - 13
PMID - 34961003
SN - 2073-4360
ER -
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BibTex (up to 50 authors)
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@article{2021_Ershova,
author = {Tatyana O Ershova and Anton A. Anisimov and Maxim Temnikov and Maxim A Novikov and Mikhail I Buzin and Galina G Nikiforova and Yulia S Dyuzhikova and Ivan E. Ushakov and Olga I Shchegolikhina and Aziz M. Muzafarov},
title = {A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters},
journal = {Polymers},
year = {2021},
volume = {13},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/polym13244452},
number = {24},
pages = {4452},
doi = {10.3390/polym13244452}
}
Cite this
MLA
Copy
Ershova, Tatyana O., et al. “A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters.” Polymers, vol. 13, no. 24, Dec. 2021, p. 4452. https://doi.org/10.3390/polym13244452.