Open Access
Polymers, volume 13, issue 24, pages 4452
A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters
Temnikov Maxim
1
,
Novikov Maxim A
2
,
Buzin Mikhail I
1
,
Nikiforova Galina G
1
,
Dyuzhikova Yulia S
1
,
Ushakov Ivan E.
1
,
Shchegolikhina Olga I
1
,
Muzafarov Aziz M.
1, 3
Publication type: Journal Article
Publication date: 2021-12-18
General Chemistry
Polymers and Plastics
Abstract
A versatile equilibrium method for synthesizing ladder-like polyphenylsilsesquioxanes (L-PPSQs) with various molecular weights (from 4 to 500 kDa) in liquid ammonia was developed. The effect of diverse parameters, such as temperature, monomer concentration, reaction time, addition or removal of water from the reaction medium, on the polycondensation process was determined. The molecular weight characteristics and structure of the L-PPSQ elements obtained were determined by GPC, 1H, 29Si NMR, IR spectroscopy, viscometry, and PXRD methods. The physicochemical properties of L-PPSQs were determined by TGA and mechanical analyses.
Citations by journals
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1
2
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Polymers
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Polymers
2 publications, 22.22%
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Reaction Chemistry and Engineering
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Reaction Chemistry and Engineering
1 publication, 11.11%
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Materials
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Materials
1 publication, 11.11%
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Silicon
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Silicon
1 publication, 11.11%
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ACS Applied Polymer Materials
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ACS Applied Polymer Materials
1 publication, 11.11%
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Macromolecules
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Macromolecules
1 publication, 11.11%
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Advanced Engineering Materials
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Advanced Engineering Materials
1 publication, 11.11%
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Polymer Science - Series C
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Polymer Science - Series C
1 publication, 11.11%
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1
2
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Citations by publishers
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1
2
3
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 33.33%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
2 publications, 22.22%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 11.11%
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Springer Nature
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Springer Nature
1 publication, 11.11%
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Wiley
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Wiley
1 publication, 11.11%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 11.11%
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1
2
3
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Ershova T. O. et al. A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters // Polymers. 2021. Vol. 13. No. 24. p. 4452.
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Ershova T. O., Anisimov A. A., Temnikov M., Novikov M. A., Buzin M. I., Nikiforova G. G., Dyuzhikova Y. S., Ushakov I. E., Shchegolikhina O. I., Muzafarov A. M. A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters // Polymers. 2021. Vol. 13. No. 24. p. 4452.
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TY - JOUR
DO - 10.3390/polym13244452
UR - https://doi.org/10.3390%2Fpolym13244452
TI - A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters
T2 - Polymers
AU - Ershova, Tatyana O
AU - Novikov, Maxim A
AU - Buzin, Mikhail I
AU - Nikiforova, Galina G
AU - Dyuzhikova, Yulia S
AU - Ushakov, Ivan E.
AU - Shchegolikhina, Olga I
AU - Anisimov, Anton A.
AU - Temnikov, Maxim
AU - Muzafarov, Aziz M.
PY - 2021
DA - 2021/12/18 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 4452
IS - 24
VL - 13
SN - 2073-4360
ER -
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@article{2021_Ershova,
author = {Tatyana O Ershova and Maxim A Novikov and Mikhail I Buzin and Galina G Nikiforova and Yulia S Dyuzhikova and Ivan E. Ushakov and Olga I Shchegolikhina and Anton A. Anisimov and Maxim Temnikov and Aziz M. Muzafarov},
title = {A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters},
journal = {Polymers},
year = {2021},
volume = {13},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {dec},
url = {https://doi.org/10.3390%2Fpolym13244452},
number = {24},
pages = {4452},
doi = {10.3390/polym13244452}
}
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MLA
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Ershova, Tatyana O., et al. “A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters.” Polymers, vol. 13, no. 24, Dec. 2021, p. 4452. https://doi.org/10.3390%2Fpolym13244452.