Open Access
Polymers, volume 14, issue 5, pages 900
Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer
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SPC UVICOM Ltd., 5 Kolontsova St., 141009 Mytischi, Russia
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Publication type: Journal Article
Publication date: 2022-02-24
PubMed ID:
35267720
General Chemistry
Polymers and Plastics
Abstract
Anionic homo- and copolymerization of p-diethynylbenzene in the presence of n-BuLi in polar solvents was carried out. The use of hexamethylphosphortriamide (HMPA) makes it possible to synthesize a completely linear soluble polymer that does not have branching and phenylene fragments. A copolymer of p-diethynylbenzene with diphenyldiacetylene was synthesized. Homo- and copolymers of p-diethynylbenzene have high thermo- and thermo-oxidative stability. By the interaction of side reactive ethynylphenylene groups with various reagents, it is proposed to synthesize clusters along the conducting chain of poly-p-diethynylbenzene. Due to presenting C≡CH side groups, boron, copper, and cobalt derivatives were synthesized. It is shown that not all theoretically possible stereoisomers can be formed as a result of the polymerization. The application of p-diethynylbenzene polymers for the modification of industrial samples of epoxy novolac resin, oligoester acrylates, and carbon fibers has been demonstrated.
Citations by journals
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2
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Polymers
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Polymers
2 publications, 66.67%
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Progress in Organic Coatings
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Progress in Organic Coatings
1 publication, 33.33%
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2
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Citations by publishers
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2
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 66.67%
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Elsevier
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Elsevier
1 publication, 33.33%
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Misin V. M. et al. Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer // Polymers. 2022. Vol. 14. No. 5. p. 900.
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Misin V. M., Maltseva I. E., Maltsev A. A., Naumkin A. V., Kazakov M. E. Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer // Polymers. 2022. Vol. 14. No. 5. p. 900.
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TY - JOUR
DO - 10.3390/polym14050900
UR - https://doi.org/10.3390%2Fpolym14050900
TI - Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer
T2 - Polymers
AU - Misin, Vyacheslav M.
AU - Maltsev, Alexander A.
AU - Kazakov, Mark E.
AU - Maltseva, Irina E.
AU - Naumkin, Alexander V.
PY - 2022
DA - 2022/02/24 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 900
IS - 5
VL - 14
PMID - 35267720
SN - 2073-4360
ER -
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@article{2022_Misin,
author = {Vyacheslav M. Misin and Alexander A. Maltsev and Mark E. Kazakov and Irina E. Maltseva and Alexander V. Naumkin},
title = {Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer},
journal = {Polymers},
year = {2022},
volume = {14},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {feb},
url = {https://doi.org/10.3390%2Fpolym14050900},
number = {5},
pages = {900},
doi = {10.3390/polym14050900}
}
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MLA
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Misin, Vyacheslav M., et al. “Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer.” Polymers, vol. 14, no. 5, Feb. 2022, p. 900. https://doi.org/10.3390%2Fpolym14050900.
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