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Polymers, volume 15, issue 5, pages 1105

The Polymers of Diethynylarenes—Is Selective Polymerization at One Acetylene Bond Possible? A Review

Misin Vyacheslav M. ¹

Maltseva Irina E. ¹

Kazakov Mark E. ²

Volkov Vladimir A. ¹

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N.M. Emanuel Institute of Biochemical Physics, Russian Academy Science, 4 Kosygina Street, 119334 Moscow, Russia |

SPC UVICOM Ltd., 38A Olympic Avenue, 141009 Mytischi, Russia |

Publication type: Journal Article

Publication date: 2023-02-22

Multidisciplinary Digital Publishing Institute (MDPI)

Journal: Polymers

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Impact factor: 5

ISSN: 20734360

DOI: 10.3390/polym15051105

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General Chemistry

Polymers and Plastics

Abstract

In this review, all available publications on the polymerization of all isomers of bifunctional diethynylarenes due to the opening of C≡C bonds were considered and analyzed. It has been shown that with the use of polymers of diethynylbenzene, heat-resistant and ablative materials, catalysts, sorbents, humidity sensors, and other materials can be obtained. Various catalytic systems and conditions of polymer synthesis are considered. For the convenience of comparison, the publications considered are grouped according to common features, including the types of initiating systems. Critical consideration is given to the features of the intramolecular structure of the synthesized polymers since it determines the entire complex of properties of this material and subsequent materials. Branched and/or insoluble polymers are formed as a result of solid-phase and liquid-phase homopolymerization. It is shown that the synthesis of a completely linear polymer was carried out for the first time by anionic polymerization. The review considers in sufficient detail publications from hard-to-reach sources, as well as publications that required a more thorough critical examination. The review does not consider the polymerization of diethynylarenes with substituted aromatic rings because of their steric restrictions; the diethynylarenes copolymers with complex intramolecular structure; and diethynylarenes polymers obtained by oxidative polycondensation.

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Microporous and Mesoporous Materials	Microporous and Mesoporous Materials, 1, 100% Microporous and Mesoporous Materials 1 publication, 100%
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Elsevier	Elsevier, 1, 100% Elsevier 1 publication, 100%
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Misin V. M. et al. The Polymers of Diethynylarenes—Is Selective Polymerization at One Acetylene Bond Possible? A Review // Polymers. 2023. Vol. 15. No. 5. p. 1105.

GOST all authors (up to 50) Copy

Misin V. M., Maltseva I. E., Kazakov M. E., Volkov V. A. The Polymers of Diethynylarenes—Is Selective Polymerization at One Acetylene Bond Possible? A Review // Polymers. 2023. Vol. 15. No. 5. p. 1105.

RIS |

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RIS Copy

TY - JOUR

DO - 10.3390/polym15051105

UR - https://doi.org/10.3390%2Fpolym15051105

TI - The Polymers of Diethynylarenes—Is Selective Polymerization at One Acetylene Bond Possible? A Review

T2 - Polymers

AU - Misin, Vyacheslav M.

AU - Maltseva, Irina E.

AU - Kazakov, Mark E.

AU - Volkov, Vladimir A.

PY - 2023

DA - 2023/02/22 00:00:00

PB - Multidisciplinary Digital Publishing Institute (MDPI)

SP - 1105

IS - 5

VL - 15

SN - 2073-4360

ER -

BibTex |

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BibTex Copy

@article{2023_Misin,

author = {Vyacheslav M. Misin and Irina E. Maltseva and Mark E. Kazakov and Vladimir A. Volkov},

title = {The Polymers of Diethynylarenes—Is Selective Polymerization at One Acetylene Bond Possible? A Review},

journal = {Polymers},

year = {2023},

volume = {15},

publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},

month = {feb},

url = {https://doi.org/10.3390%2Fpolym15051105},

number = {5},

pages = {1105},

doi = {10.3390/polym15051105}

}

MLA

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Misin, Vyacheslav M., et al. “The Polymers of Diethynylarenes—Is Selective Polymerization at One Acetylene Bond Possible? A Review.” Polymers, vol. 15, no. 5, Feb. 2023, p. 1105. https://doi.org/10.3390%2Fpolym15051105.

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Publisher

Multidisciplinary Digital Publishing Institute (MDPI)

Journal

Polymers

Quartile SCImago

Quartile WOS

Impact factor

ISSN

20734360 (Electronic)

Labs

Laboratory of Electrophysics and Radiophotonics of Composite Materials and Nanostructures