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Open access
MDPI
Processes
,  volume 11 ,  issue 11 ,  pages 3208

Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data

Publication type: Journal Article
Publication date: 2023-11-10
MDPI
scimago Q2
wos Q3
SJR: 0.554
CiteScore: 5.5
Impact factor: 2.8
ISSN: 22279717
Process Chemistry and Technology
Bioengineering
Chemical Engineering (miscellaneous)
Abstract

New physicochemical data for trans-perfluorodecalin (trans-PDF) and cis-perfluorodecalin (cis-PFD) are presented. Based on the differential scanning calorimetry, the temperature and heat of the solid−liquid phase transition are determined. The coefficients of Antoine’s equation are calculated based on the experimental temperature–pressure dependence data. This article also presents data on the rheological properties («zero» shear viscosity and apparent activation energy for the viscous flow) of the studied compounds. The dependencies of refractive index and excess volume (density) on temperature are studied. Gas chromatography–mass spectrometry data and FTIR, 13C NMR, and 19F NMR spectra are provided. The dependencies are given for the perfluoro(butylcyclohexane) (BCH)–trans-PFD, BCH–cis-PFD, and trans-PFD–cis-PFD binary systems and BCH–trans-PFD–cis-PFD ternary system: refractive index and density (liquid molar volume and excess molar volume) of composition and temperature. The dependences of the excess molar volume on the composition and temperature of the mixtures are correlated with Redlich-Kister and Kohler equations.

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Lupachev E. V. et al. Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data // Processes. 2023. Vol. 11. No. 11. p. 3208.
GOST all authors (up to 50) Copy
Lupachev E. V., Voshkin A. A., Kisel’ A. V., Kulov N. N., Zakhodyaeva Y. A., Polkovnichenko A. V. Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data // Processes. 2023. Vol. 11. No. 11. p. 3208.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3390/pr11113208
UR - https://doi.org/10.3390/pr11113208
TI - Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data
T2 - Processes
AU - Lupachev, Egor V.
AU - Voshkin, Andrey A
AU - Kisel’, Alexey V.
AU - Kulov, Nikolai N
AU - Zakhodyaeva, Yulia A
AU - Polkovnichenko, Andrei V.
PY - 2023
DA - 2023/11/10
PB - MDPI
SP - 3208
IS - 11
VL - 11
SN - 2227-9717
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Lupachev,
author = {Egor V. Lupachev and Andrey A Voshkin and Alexey V. Kisel’ and Nikolai N Kulov and Yulia A Zakhodyaeva and Andrei V. Polkovnichenko},
title = {Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data},
journal = {Processes},
year = {2023},
volume = {11},
publisher = {MDPI},
month = {nov},
url = {https://doi.org/10.3390/pr11113208},
number = {11},
pages = {3208},
doi = {10.3390/pr11113208}
}
MLA
Cite this
MLA Copy
Lupachev, Egor V., et al. “Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data.” Processes, vol. 11, no. 11, Nov. 2023, p. 3208. https://doi.org/10.3390/pr11113208.