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Sensors, volume 21, issue 24, pages 8472

Evaluating the Response Time of an Optical Gas Sensor Based on Gasochromic Nanostructures

Nechepurenko Igor A 1, 2
Kulikova Daria P 1, 3
Kornienko Vladimir V. 1, 3
Afanasiev Konstantin N 1, 4
Shekoyan Landzhik A 5
Dorofeenko A V 1, 2, 4
Publication typeJournal Article
Publication date2021-12-19
Journal: Sensors
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor3.9
ISSN14243210, 14248220
PubMed ID:  34960565
Biochemistry
Analytical Chemistry
Atomic and Molecular Physics, and Optics
Electrical and Electronic Engineering
Instrumentation
Abstract

We propose a method for determining complex dielectric permittivity dynamics in the gasochromic oxides in the course of their interaction with a gas as well as for estimating the diffusion coefficient into a gasochromic oxide layer. The method is based on analysis of a time evolution of reflection spectra measured in the Kretschmann configuration. The method is demonstrated with a hydrogen-sensitive trilayer including an Au plasmonic film, WO3 gasochromic oxide layer, and Pt catalyst. Angular dependences of the reflectance as well as transmission spectra of the trilayer were measured in series at a constant flow of gas mixtures with hydrogen concentrations in a range of 0–0.36%, and a detection limit below 40 ppm (0.004%) of H2 was demonstrated. Response times to hydrogen were found in different ways. We show that the dielectric permittivity dynamics of WO3 must be retrieved in order to correctly evaluate the response time, whereas a direct evaluation from intensity changes for chosen wavelengths may have a high discrepancy. The proposed method gives insight into the optical properties dynamics for sensing elements based on gasochromic nanostructures.

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Nechepurenko I. A. et al. Evaluating the Response Time of an Optical Gas Sensor Based on Gasochromic Nanostructures // Sensors. 2021. Vol. 21. No. 24. p. 8472.
GOST all authors (up to 50) Copy
Nechepurenko I. A., Kulikova D. P., Kornienko V. V., Afanasiev K. N., Shekoyan L. A., Baryshev A. V., Dorofeenko A. V. Evaluating the Response Time of an Optical Gas Sensor Based on Gasochromic Nanostructures // Sensors. 2021. Vol. 21. No. 24. p. 8472.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.3390/s21248472
UR - https://doi.org/10.3390%2Fs21248472
TI - Evaluating the Response Time of an Optical Gas Sensor Based on Gasochromic Nanostructures
T2 - Sensors
AU - Nechepurenko, Igor A
AU - Kulikova, Daria P
AU - Afanasiev, Konstantin N
AU - Shekoyan, Landzhik A
AU - Baryshev, Alexander V
AU - Kornienko, Vladimir V.
AU - Dorofeenko, A V
PY - 2021
DA - 2021/12/19 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 8472
IS - 24
VL - 21
PMID - 34960565
SN - 1424-3210
SN - 1424-8220
ER -
BibTex |
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BibTex Copy
@article{2021_Nechepurenko,
author = {Igor A Nechepurenko and Daria P Kulikova and Konstantin N Afanasiev and Landzhik A Shekoyan and Alexander V Baryshev and Vladimir V. Kornienko and A V Dorofeenko},
title = {Evaluating the Response Time of an Optical Gas Sensor Based on Gasochromic Nanostructures},
journal = {Sensors},
year = {2021},
volume = {21},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {dec},
url = {https://doi.org/10.3390%2Fs21248472},
number = {24},
pages = {8472},
doi = {10.3390/s21248472}
}
MLA
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MLA Copy
Nechepurenko, Igor A., et al. “Evaluating the Response Time of an Optical Gas Sensor Based on Gasochromic Nanostructures.” Sensors, vol. 21, no. 24, Dec. 2021, p. 8472. https://doi.org/10.3390%2Fs21248472.
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