Open Access

Lubricants

, volume 8 , issue 5 , pages 50

Methylenealkane-based low-viscosity ester oils: Synthesis and outlook

Ilya E. Nifant'ev ^{1, 2}

Vladimir Bagrov ²

Alexander Vinogradov ¹

Alexey Vinogradov ¹

Sergey O. Ilyin ¹

Nadezhda Sevostyanova ³

Sergey Batashev ³

Pavel V Ivchenko ^{1, 2}

Hide authors affiliations Show authors affiliations: 3 affiliations

A.V. Topchiev Institute of Petrochemical Synthesis RAS, 29 Leninsky Pr., 119991 Moscow, Russia |

Chemistry Department, M.V. Lomonosov Moscow State University, 1 Leninskie Gory Str., Building 3, 119991 Moscow, Russia |

Chemistry Department, Tula State Lev Tolstoy Pedagogical University, 125 Lenin Prospect, 300026 Tula, Russia |

Publication type: Journal Article

Publication date: 2020-05-02

MDPI

Lubricants

scimago Q2

wos Q2

SJR: 0.536

CiteScore: 4.5

Impact factor: 2.9

ISSN: 20754442

DOI: 10.3390/LUBRICANTS8050050

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Surfaces, Coatings and Films

Mechanical Engineering

Abstract

Both Group 4 poly-α-olefin (PAO) and Group 5 ester oil basestocks are used in formulations of synthetic engine oils, transmission fluids, and lubricants with leading characteristics such as low viscosity (providing fuel saving), high stability, and environmental safety. The modern technologies of the production of PAOs use catalytic oligomerization of α-olefins, which is complicated by the formation of low-molecular-weight α-olefin dimers (methylenealkanes) as imminent side products. The use of methylenealkanes as raw materials for the synthesis of Group 5 base stocks appears to be highly promising. In the present work, we report the use of methyl 3-butylnonanoate and methyl 3-hexylundecanoate, the products of catalytic methoxycarbonylation of hex-1-ene and oct-1-ene dimers, in the synthesis of two series of branched isomeric esters. These esters demonstrated excellent rheological behavior and may be considered as low-viscosity engine oils with leading characteristics.

Found

4 citations

Ilyin Sergey

PhD in Chemistry

142 publications, 2 992 citations, 623 reviews

h-index: 34

A.V. Topchiev Institute of Petrochemical Synthesis RAS

High molecular weight compounds

Rheology

1 citation

Parfenova Lyudmila

🥼 🤝

DSc in Chemistry, associate professor

109 publications, 1 037 citations, 8 reviews

h-index: 17

Institute of Petrochemistry and Catalysis of the Ufa Federal Research Center of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

Regenerative materials

1 citation

Borisov Roman

🤝

PhD in Chemistry

184 publications, 1 708 citations, 19 reviews

h-index: 20

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Peoples' Friendship University of Russia

Research interests

Mass Spectrometry

1 citation

Bermeshev Maxim

🥼 🤝

DSc in Chemistry, associate professor, associate member of the Russian Academy of Sciences

208 publications, 2 829 citations, 43 reviews

h-index: 27

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

Research interests

Metathesis polymerization

1 citation

Wozniak Alyona

PhD in Chemistry

37 publications, 398 citations

h-index: 11

A.V. Topchiev Institute of Petrochemical Synthesis RAS

1 citation

Morontsev Aleksandr

PhD in Chemistry

16 publications, 161 citations, 1 review

h-index: 7

A.V. Topchiev Institute of Petrochemical Synthesis RAS

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Nifant'ev I. E. et al. Methylenealkane-based low-viscosity ester oils: Synthesis and outlook // Lubricants. 2020. Vol. 8. No. 5. p. 50.

GOST all authors (up to 50) Copy

Nifant'ev I. E., Bagrov V., Vinogradov A., Vinogradov A., Ilyin S. O., Sevostyanova N., Batashev S., Ivchenko P. V. Methylenealkane-based low-viscosity ester oils: Synthesis and outlook // Lubricants. 2020. Vol. 8. No. 5. p. 50.

RIS |

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RIS Copy

TY - JOUR

DO - 10.3390/LUBRICANTS8050050

UR - https://www.mdpi.com/2075-4442/8/5/50

TI - Methylenealkane-based low-viscosity ester oils: Synthesis and outlook

T2 - Lubricants

AU - Nifant'ev, Ilya E.

AU - Bagrov, Vladimir

AU - Vinogradov, Alexander

AU - Vinogradov, Alexey

AU - Ilyin, Sergey O.

AU - Sevostyanova, Nadezhda

AU - Batashev, Sergey

AU - Ivchenko, Pavel V

PY - 2020

DA - 2020/05/02

PB - MDPI

SP - 50

IS - 5

VL - 8

SN - 2075-4442

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2020_Nifant'ev,

author = {Ilya E. Nifant'ev and Vladimir Bagrov and Alexander Vinogradov and Alexey Vinogradov and Sergey O. Ilyin and Nadezhda Sevostyanova and Sergey Batashev and Pavel V Ivchenko},

title = {Methylenealkane-based low-viscosity ester oils: Synthesis and outlook},

journal = {Lubricants},

year = {2020},

volume = {8},

publisher = {MDPI},

month = {may},

url = {https://www.mdpi.com/2075-4442/8/5/50},

number = {5},

pages = {50},

doi = {10.3390/LUBRICANTS8050050}

}

MLA

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MLA Copy

Nifant'ev, Ilya E., et al. “Methylenealkane-based low-viscosity ester oils: Synthesis and outlook.” Lubricants, vol. 8, no. 5, May. 2020, p. 50. https://www.mdpi.com/2075-4442/8/5/50.

Publisher

MDPI

Journal

Lubricants

scimago Q2

wos Q2

SJR

0.536

CiteScore

4.5

Impact factor

2.9

ISSN

20754442 (Electronic)

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