Open Access
Open access
MDPI
MolBank
,  volume 2020 ,  issue 4 ,  pages M1174

6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II)

Publication type: Journal Article
Publication date: 2020-12-03
MDPI
scimago Q4
wos Q4
SJR: 0.142
CiteScore: 0.9
Impact factor: 0.4
ISSN: 14228599
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract

Polymeric nickel complexes of salen ligands meet a wide range of applications in catalysis and electrochemistry. Because these polymers usually form very rigid films, the introduction of the conformationally flexible fragments in the corresponding monomers favors the amorphization and, thus, the mass transport. Herein we report a preparation of the hexyloxy-substituted monomeric NiSalen complex by the direct alkylation of the hydroxy-substituted complex. The resulting product was characterized by the 1H and 13C nuclear magnetic resonance (NMR), ESI-high resolution mass spectrometry (ESI-HRMS, and Fourier-transform infrared spectroscopy (FTIR). The crystal structure of the product was examined by an XRD, indicating the formation of the solvate with dichloromethane. The obtained product was found to be highly soluble in non-polar solvents, in contrast to typical NiSalens.

Found 

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
0
Share
Cite this
GOST |
Cite this
GOST Copy
Lukyanov D. A., Borisova A. S., Levin O. V. 6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II) // MolBank. 2020. Vol. 2020. No. 4. p. M1174.
GOST all authors (up to 50) Copy
Lukyanov D. A., Borisova A. S., Levin O. V. 6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II) // MolBank. 2020. Vol. 2020. No. 4. p. M1174.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.3390/M1174
UR - https://doi.org/10.3390/M1174
TI - 6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II)
T2 - MolBank
AU - Lukyanov, Daniil A
AU - Borisova, Anna S
AU - Levin, Oleg V.
PY - 2020
DA - 2020/12/03
PB - MDPI
SP - M1174
IS - 4
VL - 2020
SN - 1422-8599
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Lukyanov,
author = {Daniil A Lukyanov and Anna S Borisova and Oleg V. Levin},
title = {6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II)},
journal = {MolBank},
year = {2020},
volume = {2020},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/M1174},
number = {4},
pages = {M1174},
doi = {10.3390/M1174}
}
MLA
Cite this
MLA Copy
Lukyanov, Daniil A., et al. “6,6′-{[Ethane-1,2-diylbis(azaneylylidene)]bis(methaneylylidene)}bis[2-(hexyloxy)phenolato] Nickel(II).” MolBank, vol. 2020, no. 4, Dec. 2020, p. M1174. https://doi.org/10.3390/M1174.