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(2aR,2a1S,5aR,9bR)-4-Isopropyl-7,8-dimethoxy-2a1-methyl-2,2a,2a1,3,5a,9b-hexahydrofluoreno[9,1-bc]furan
Irina V Ilyina
1
,
N S Li Zhulanov
1
,
Yuri V. Gatilov
1
,
Alexander Yu Sidorenko
2
,
Vladimir E Agabekov
2
,
Nariman F. Salakhutdinov
1
Publication type: Journal Article
Publication date: 2023-10-09
DOI:
10.3390/m1734
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The development of highly efficient methods for the synthesis of chemical products by using renewable raw materials is one of the topical areas of medicinal chemistry. The paper presents the synthesis of (2aR,2a1S,5aR,9bR)-4-isopropyl-7,8-dimethoxy-2a1-methyl-2,2a,2a1,3,5a,9b-hexahydrofluoreno[9,1-bc]furan. The title compound was obtained through Prins–Friedel–Crafts cascade reactions of trans-4-hydroxymethyl-2-carene, which was synthesized from 3-carene, one of the main components of gum turpentine. The product yield after purification was 48%. The compound’s structure was confirmed by X-ray diffraction analysis.
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Total citations:
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Citations from 2024:
3
(100%)
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Ilyina I. V. et al. (2aR,2a1S,5aR,9bR)-4-Isopropyl-7,8-dimethoxy-2a1-methyl-2,2a,2a1,3,5a,9b-hexahydrofluoreno[9,1-bc]furan // MolBank. 2023. Vol. 2023. No. 4. p. M1734.
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Ilyina I. V., Li Zhulanov N. S., Gatilov Y. V., Volcho K. P., Sidorenko A. Yu., Agabekov V. E., Salakhutdinov N. F. (2aR,2a1S,5aR,9bR)-4-Isopropyl-7,8-dimethoxy-2a1-methyl-2,2a,2a1,3,5a,9b-hexahydrofluoreno[9,1-bc]furan // MolBank. 2023. Vol. 2023. No. 4. p. M1734.
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TY - JOUR
DO - 10.3390/m1734
UR - https://doi.org/10.3390/m1734
TI - (2aR,2a1S,5aR,9bR)-4-Isopropyl-7,8-dimethoxy-2a1-methyl-2,2a,2a1,3,5a,9b-hexahydrofluoreno[9,1-bc]furan
T2 - MolBank
AU - Ilyina, Irina V
AU - Li Zhulanov, N S
AU - Gatilov, Yuri V.
AU - Volcho, Konstantin P.
AU - Sidorenko, Alexander Yu
AU - Agabekov, Vladimir E
AU - Salakhutdinov, Nariman F.
PY - 2023
DA - 2023/10/09
PB - MDPI
SP - M1734
IS - 4
VL - 2023
SN - 1422-8599
ER -
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@article{2023_Ilyina,
author = {Irina V Ilyina and N S Li Zhulanov and Yuri V. Gatilov and Konstantin P. Volcho and Alexander Yu Sidorenko and Vladimir E Agabekov and Nariman F. Salakhutdinov},
title = {(2aR,2a1S,5aR,9bR)-4-Isopropyl-7,8-dimethoxy-2a1-methyl-2,2a,2a1,3,5a,9b-hexahydrofluoreno[9,1-bc]furan},
journal = {MolBank},
year = {2023},
volume = {2023},
publisher = {MDPI},
month = {oct},
url = {https://doi.org/10.3390/m1734},
number = {4},
pages = {M1734},
doi = {10.3390/m1734}
}
Cite this
MLA
Copy
Ilyina, Irina V., et al. “(2aR,2a1S,5aR,9bR)-4-Isopropyl-7,8-dimethoxy-2a1-methyl-2,2a,2a1,3,5a,9b-hexahydrofluoreno[9,1-bc]furan.” MolBank, vol. 2023, no. 4, Oct. 2023, p. M1734. https://doi.org/10.3390/m1734.
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