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Sensors, volume 20, issue 17, pages 4832

A Comparative Study on the Oxidation of Label-Free Silver Triangular Nanoplates by Peroxides: Main Effects and Sensing Applications

Publication typeJournal Article
Publication date2020-08-27
Journal: Sensors
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor3.9
ISSN14243210, 14248220
PubMed ID:  32867039
Biochemistry
Analytical Chemistry
Atomic and Molecular Physics, and Optics
Electrical and Electronic Engineering
Instrumentation
Abstract

Nowadays, analytical systems based on silver triangular nanoplates (AgTNPs) have been shown as good prospects for chemical sensing. However, they still remain relatively poorly studied as colorimetric probes for sensing various classes of compounds. This study shows that these nanoparticles are capable of being oxidized by peroxides, including both hydrogen peroxide and its organic derivatives. The oxidation was found to result in a decrease in the AgTNPs’ local surface plasmon resonance band intensity at 620 nm. This was proposed for peroxide-sensitive spectrophotometric determination. Five peroxides differing in their structure and number of functional groups were tested. Three of them easily oxidized AgTNPs. The effects of a structure of analytes and main exterior factors on the oxidation are discussed. The detection limits of peroxides in the selected conditions increased in the series peracetic acid < hydrogen peroxide < tert-butyl hydroperoxide, coming to 0.08, 1.6 and 24 μmol L−1, respectively. tert-Butyl peroxybenzoate and di-tert-butyl peroxide were found to have no effect on the spectral characteristics of AgTNPs. By the example of hydrogen peroxide, it was found that the determination does not interfere with 100–4000-fold quantities of common inorganic ions. The proposed approach was successfully applied to the analysis of drugs, cosmetics and model mixtures.

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Furletov A. A. et al. A Comparative Study on the Oxidation of Label-Free Silver Triangular Nanoplates by Peroxides: Main Effects and Sensing Applications // Sensors. 2020. Vol. 20. No. 17. p. 4832.
GOST all authors (up to 50) Copy
Furletov A. A., Apyari V., Garshev A., Dmitrienko S. A Comparative Study on the Oxidation of Label-Free Silver Triangular Nanoplates by Peroxides: Main Effects and Sensing Applications // Sensors. 2020. Vol. 20. No. 17. p. 4832.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3390/S20174832
UR - https://doi.org/10.3390%2FS20174832
TI - A Comparative Study on the Oxidation of Label-Free Silver Triangular Nanoplates by Peroxides: Main Effects and Sensing Applications
T2 - Sensors
AU - Garshev, Alexey
AU - Dmitrienko, Stanislava
AU - Furletov, Aleksei A
AU - Apyari, Vladimir
PY - 2020
DA - 2020/08/27 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 4832
IS - 17
VL - 20
PMID - 32867039
SN - 1424-3210
SN - 1424-8220
ER -
BibTex |
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BibTex Copy
@article{2020_Furletov,
author = {Alexey Garshev and Stanislava Dmitrienko and Aleksei A Furletov and Vladimir Apyari},
title = {A Comparative Study on the Oxidation of Label-Free Silver Triangular Nanoplates by Peroxides: Main Effects and Sensing Applications},
journal = {Sensors},
year = {2020},
volume = {20},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {aug},
url = {https://doi.org/10.3390%2FS20174832},
number = {17},
pages = {4832},
doi = {10.3390/S20174832}
}
MLA
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MLA Copy
Furletov, Aleksei A., et al. “A Comparative Study on the Oxidation of Label-Free Silver Triangular Nanoplates by Peroxides: Main Effects and Sensing Applications.” Sensors, vol. 20, no. 17, Aug. 2020, p. 4832. https://doi.org/10.3390%2FS20174832.
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