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volume 4 issue 4 pages 61

Sodium Rechargeable Batteries with Electrolytes Based on Nafion Membranes Intercalated by Mixtures of Organic Solvents

Publication typeJournal Article
Publication date2018-12-01
scimago Q1
wos Q2
SJR0.825
CiteScore6.6
Impact factor4.8
ISSN23130105
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Abstract

The possibilities of manufacturing batteries with Nafion 117 membranes in the Na+-form intercalated by mixtures of non-aqueous organic solvents used both as an electrolyte, separator, and binder were investigated. Electrochemical stability of various organic solvent mixtures based on N,N-dimethylacetamide, ethylene carbonate, propylene carbonate, and tetrahydrofuran were characterized. It was shown that a sodium battery based on a Nafion-Na membrane intercalated by mixture of ethylene carbonate and propylene carbonate with a Na3V1.9Fe0.1(PO4)3/C positive electrode is characterized by a discharge capacity of ≈110 mAh·g−1 (current density of 10 mA·g−1) at room temperature and shows the ability to cycle without degradation during 20 cycles. Batteries with Nafion membrane electrolytes, containing N,N-dimethylacetamide, were characterized using capacity fading during cycling, which is due to the interaction of N,N-dimethylacetamide and a negative sodium electrode.

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GOST |
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GOST Copy
Kulova T. et al. Sodium Rechargeable Batteries with Electrolytes Based on Nafion Membranes Intercalated by Mixtures of Organic Solvents // Batteries. 2018. Vol. 4. No. 4. p. 61.
GOST all authors (up to 50) Copy
Kulova T., Skundin A., Chekannikov A., Novikova S., Voropaeva D., Yaroslavtsev A. Sodium Rechargeable Batteries with Electrolytes Based on Nafion Membranes Intercalated by Mixtures of Organic Solvents // Batteries. 2018. Vol. 4. No. 4. p. 61.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3390/batteries4040061
UR - https://doi.org/10.3390/batteries4040061
TI - Sodium Rechargeable Batteries with Electrolytes Based on Nafion Membranes Intercalated by Mixtures of Organic Solvents
T2 - Batteries
AU - Kulova, Tatiana
AU - Skundin, Alexander
AU - Chekannikov, Andrey
AU - Novikova, Svetlana
AU - Voropaeva, Daria
AU - Yaroslavtsev, Andrey
PY - 2018
DA - 2018/12/01
PB - MDPI
SP - 61
IS - 4
VL - 4
SN - 2313-0105
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Kulova,
author = {Tatiana Kulova and Alexander Skundin and Andrey Chekannikov and Svetlana Novikova and Daria Voropaeva and Andrey Yaroslavtsev},
title = {Sodium Rechargeable Batteries with Electrolytes Based on Nafion Membranes Intercalated by Mixtures of Organic Solvents},
journal = {Batteries},
year = {2018},
volume = {4},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/batteries4040061},
number = {4},
pages = {61},
doi = {10.3390/batteries4040061}
}
MLA
Cite this
MLA Copy
Kulova, Tatiana, et al. “Sodium Rechargeable Batteries with Electrolytes Based on Nafion Membranes Intercalated by Mixtures of Organic Solvents.” Batteries, vol. 4, no. 4, Dec. 2018, p. 61. https://doi.org/10.3390/batteries4040061.