Open Access
Batteries, volume 9, issue 1, pages 59
NASICON-Type Li1+xAlxZryTi2−x−y(PO4)3 Solid Electrolytes: Effect of Al, Zr Co-Doping and Synthesis Method
Publication type: Journal Article
Publication date: 2023-01-15
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Abstract
Replacing liquid electrolytes with solid-state conductors is one of the key challenges to increasing the safety and energy density of next-generation Li secondary batteries. In this work, the NASICON-type Li1+xAlxZryTi2−x−y(PO4)3 with 0 ≤ x, y ≤ 0.2 solid electrolytes were synthesized using solid-state and sol-gel techniques at various sintering temperatures (800, 900, and 1000 °C). Their morphology and conducting properties were studied to determine the optimal dopant content and synthesis method. Li1.2Al0.2Zr0.1Ti1.7(PO4)3 and Li1.1Al0.1Zr0.2Ti1.7(PO4)3 prepared at 900 °C using a solid-state reaction exhibit the highest total conductivity at 25 °C (7.9 × 10−4 and 5.4 × 10−4 S cm−1, respectively), which is due to the optimal size of lithium transport channels, as well as the high density of these samples. The potential profile of Li|Li1.2Al0.2Zr0.1Ti1.7(PO4)3|Li cells was retained during cycling at a current density of 0.05 mA cm−2 for 100 h, indicating a high interfacial Li metal/electrolyte stability.
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- We do not take into account publications without a DOI.
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Stenina I. A., Pyrkova A., Yaroslavtsev A. B. NASICON-Type Li1+xAlxZryTi2−x−y(PO4)3 Solid Electrolytes: Effect of Al, Zr Co-Doping and Synthesis Method // Batteries. 2023. Vol. 9. No. 1. p. 59.
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Stenina I. A., Pyrkova A., Yaroslavtsev A. B. NASICON-Type Li1+xAlxZryTi2−x−y(PO4)3 Solid Electrolytes: Effect of Al, Zr Co-Doping and Synthesis Method // Batteries. 2023. Vol. 9. No. 1. p. 59.
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TY - JOUR
DO - 10.3390/batteries9010059
UR - https://doi.org/10.3390/batteries9010059
TI - NASICON-Type Li1+xAlxZryTi2−x−y(PO4)3 Solid Electrolytes: Effect of Al, Zr Co-Doping and Synthesis Method
T2 - Batteries
AU - Stenina, Irina A
AU - Pyrkova, Anastasia
AU - Yaroslavtsev, A. B.
PY - 2023
DA - 2023/01/15 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 59
IS - 1
VL - 9
SN - 2313-0105
ER -
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@article{2023_Stenina,
author = {Irina A Stenina and Anastasia Pyrkova and A. B. Yaroslavtsev},
title = {NASICON-Type Li1+xAlxZryTi2−x−y(PO4)3 Solid Electrolytes: Effect of Al, Zr Co-Doping and Synthesis Method},
journal = {Batteries},
year = {2023},
volume = {9},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {jan},
url = {https://doi.org/10.3390/batteries9010059},
number = {1},
pages = {59},
doi = {10.3390/batteries9010059}
}
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Stenina, Irina A., et al. “NASICON-Type Li1+xAlxZryTi2−x−y(PO4)3 Solid Electrolytes: Effect of Al, Zr Co-Doping and Synthesis Method.” Batteries, vol. 9, no. 1, Jan. 2023, p. 59. https://doi.org/10.3390/batteries9010059.
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