Open Access
Palladium PEPPSI-IPr Complex Supported on a Calix[8]arene: A New Catalyst for Efficient Suzuki–Miyaura Coupling of Aryl Chlorides
Axel Labattut
1
,
Ibrahim Abdellah
1
,
Julien Buendia
2
,
Sandra Abi Fayssal
1, 2
,
Erika Adhel
1
,
Diana Dragoe
1
,
Cyril Martini
2
,
Vincent Huc
1
2
NOVECAL, 86 rue de Paris, 91400 Orsay, France
|
Publication type: Journal Article
Publication date: 2020-09-18
Catalysis
Physical and Theoretical Chemistry
Abstract
We report here the synthesis and characterization of a new calix[8]arene-supported PEPPSI-IPr Pd polymetallic complex. This complex, showing greater steric hindrance around the Pd centers compared with previous calix[8]arene-based catalysts, demonstrated high reactivity and selectivity for the Suzuki–Miyaura coupling of aryl chlorides under mild conditions. Along with this good performance, the new catalyst showed low Pd leaching into the final Suzuki–Miyaura coupling products, indicative of a heterogeneous-type reactivity. This rare combination of good reactivity towards challenging substrates and low metal leaching offers great promise at both academic and industrial levels.
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11
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GOST
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Labattut A. et al. Palladium PEPPSI-IPr Complex Supported on a Calix[8]arene: A New Catalyst for Efficient Suzuki–Miyaura Coupling of Aryl Chlorides // Catalysts. 2020. Vol. 10. No. 9. p. 1081.
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Labattut A., Abdellah I., Buendia J., Abi Fayssal S., Adhel E., Dragoe D., Martini C., Schulz E., Huc V. Palladium PEPPSI-IPr Complex Supported on a Calix[8]arene: A New Catalyst for Efficient Suzuki–Miyaura Coupling of Aryl Chlorides // Catalysts. 2020. Vol. 10. No. 9. p. 1081.
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RIS
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TY - JOUR
DO - 10.3390/catal10091081
UR - https://doi.org/10.3390/catal10091081
TI - Palladium PEPPSI-IPr Complex Supported on a Calix[8]arene: A New Catalyst for Efficient Suzuki–Miyaura Coupling of Aryl Chlorides
T2 - Catalysts
AU - Labattut, Axel
AU - Abdellah, Ibrahim
AU - Buendia, Julien
AU - Abi Fayssal, Sandra
AU - Adhel, Erika
AU - Dragoe, Diana
AU - Martini, Cyril
AU - Schulz, Emmanuelle
AU - Huc, Vincent
PY - 2020
DA - 2020/09/18
PB - MDPI
SP - 1081
IS - 9
VL - 10
SN - 2073-4344
ER -
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BibTex (up to 50 authors)
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@article{2020_Labattut,
author = {Axel Labattut and Ibrahim Abdellah and Julien Buendia and Sandra Abi Fayssal and Erika Adhel and Diana Dragoe and Cyril Martini and Emmanuelle Schulz and Vincent Huc},
title = {Palladium PEPPSI-IPr Complex Supported on a Calix[8]arene: A New Catalyst for Efficient Suzuki–Miyaura Coupling of Aryl Chlorides},
journal = {Catalysts},
year = {2020},
volume = {10},
publisher = {MDPI},
month = {sep},
url = {https://doi.org/10.3390/catal10091081},
number = {9},
pages = {1081},
doi = {10.3390/catal10091081}
}
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MLA
Copy
Labattut, Axel, et al. “Palladium PEPPSI-IPr Complex Supported on a Calix[8]arene: A New Catalyst for Efficient Suzuki–Miyaura Coupling of Aryl Chlorides.” Catalysts, vol. 10, no. 9, Sep. 2020, p. 1081. https://doi.org/10.3390/catal10091081.