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Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine
Тип публикации: Journal Article
Дата публикации: 2021-03-29
Catalysis
Physical and Theoretical Chemistry
Краткое описание
The epoxidation of turpentine (technical α-pinene), 3-carene, and limonene with aqueous hydrogen peroxide was studied in a new catalytic system employing manganese sulfate, salicylic acid, sodium bicarbonate, and acetonitrile, as a polar solvent. The proposed approach makes it possible to carry out a “chemical separation” of turpentine components, yielding valuable individual derivatives of monoterpenes without the need to isolate individual monoterpene reagents. Specific methods have been developed for the production of α-pinene epoxide, 3-carene epoxide, limonene diepoxide, as well as for two related compounds: 3-carene-5-one and 3-carene-2,5-dione.
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Fomenko V., Laev S. S., Salakhutdinov N. F. Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine // Catalysts. 2021. Vol. 11. No. 4. p. 436.
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Fomenko V., Laev S. S., Salakhutdinov N. F. Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine // Catalysts. 2021. Vol. 11. No. 4. p. 436.
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TY - JOUR
DO - 10.3390/catal11040436
UR - https://doi.org/10.3390/catal11040436
TI - Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine
T2 - Catalysts
AU - Fomenko, Vladislav
AU - Laev, Sergey S
AU - Salakhutdinov, Nariman F.
PY - 2021
DA - 2021/03/29
PB - MDPI
SP - 436
IS - 4
VL - 11
SN - 2073-4344
ER -
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@article{2021_Fomenko,
author = {Vladislav Fomenko and Sergey S Laev and Nariman F. Salakhutdinov},
title = {Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine},
journal = {Catalysts},
year = {2021},
volume = {11},
publisher = {MDPI},
month = {mar},
url = {https://doi.org/10.3390/catal11040436},
number = {4},
pages = {436},
doi = {10.3390/catal11040436}
}
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Fomenko, Vladislav, et al. “Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine.” Catalysts, vol. 11, no. 4, Mar. 2021, p. 436. https://doi.org/10.3390/catal11040436.
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