Open Access
Semi-Hydrogenation of Acetylene to Ethylene Catalyzed by Bimetallic CuNi/ZSM-12 Catalysts
Song Hu
1
,
Chong Zhang
2
,
Mingyu Wu
2
,
Runping Ye
2
,
Depan Shi
1
,
Mujin Li
1
,
Peng Zhao
1
,
Rongbin Zhang
2
,
Gang Feng
2
1
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Department of Process Development and Design, Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China
|
Publication type: Journal Article
Publication date: 2022-09-19
Catalysis
Physical and Theoretical Chemistry
General Environmental Science
Abstract
The purpose of this work is to develop a low-cost and high-performance catalyst for the selective catalytic hydrogenation of acetylene to ethylene. Non-precious metals Cu and Ni were selected as active ingredients for this study. Using ZSM-12 as a carrier, Cu-Ni bimetallic catalysts of CuNix/ZSM-12 (x = 5, 7, 9, 11) with different Ni/Cu ratios were prepared by incipient wetness impregnation method. The total Cu and Ni loading were 2 wt%. Under the optimal reaction conditions, the acetylene conversion was 100%, and the ethylene selectivity was 82.48%. The CuNi7/ZSM-12 prepared in this work exhibits good performance in the semi-hydrogenation of acetylene to ethylene with low cost and has potential for industrial application.
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Total citations:
13
Citations from 2024:
10
(76.92%)
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MLA
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GOST
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Hu S. et al. Semi-Hydrogenation of Acetylene to Ethylene Catalyzed by Bimetallic CuNi/ZSM-12 Catalysts // Catalysts. 2022. Vol. 12. No. 9. p. 1072.
GOST all authors (up to 50)
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Hu S., Zhang C., Wu M., Ye R., Shi D., Li M., Zhao P., Zhang R., Feng G. Semi-Hydrogenation of Acetylene to Ethylene Catalyzed by Bimetallic CuNi/ZSM-12 Catalysts // Catalysts. 2022. Vol. 12. No. 9. p. 1072.
Cite this
RIS
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TY - JOUR
DO - 10.3390/catal12091072
UR - https://doi.org/10.3390/catal12091072
TI - Semi-Hydrogenation of Acetylene to Ethylene Catalyzed by Bimetallic CuNi/ZSM-12 Catalysts
T2 - Catalysts
AU - Hu, Song
AU - Zhang, Chong
AU - Wu, Mingyu
AU - Ye, Runping
AU - Shi, Depan
AU - Li, Mujin
AU - Zhao, Peng
AU - Zhang, Rongbin
AU - Feng, Gang
PY - 2022
DA - 2022/09/19
PB - MDPI
SP - 1072
IS - 9
VL - 12
SN - 2073-4344
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Hu,
author = {Song Hu and Chong Zhang and Mingyu Wu and Runping Ye and Depan Shi and Mujin Li and Peng Zhao and Rongbin Zhang and Gang Feng},
title = {Semi-Hydrogenation of Acetylene to Ethylene Catalyzed by Bimetallic CuNi/ZSM-12 Catalysts},
journal = {Catalysts},
year = {2022},
volume = {12},
publisher = {MDPI},
month = {sep},
url = {https://doi.org/10.3390/catal12091072},
number = {9},
pages = {1072},
doi = {10.3390/catal12091072}
}
Cite this
MLA
Copy
Hu, Song, et al. “Semi-Hydrogenation of Acetylene to Ethylene Catalyzed by Bimetallic CuNi/ZSM-12 Catalysts.” Catalysts, vol. 12, no. 9, Sep. 2022, p. 1072. https://doi.org/10.3390/catal12091072.