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Carbozincation of Substituted 2-Alkynylamines, 1-Alkynylphosphines, 1-Alkynylphosphine Sulfides with Et2Zn in the Presence of Catalytic System of Ti(O-iPr)4 and EtMgBr
Publication type: Journal Article
Publication date: 2019-12-04
Catalysis
Physical and Theoretical Chemistry
Abstract
The EtMgBr and Ti(O-iPr)4-catalyzed ethylzincation of 1-alkynylphosphine sulfides with Et2Zn in diethyl ether followed by hydrolysis and deuterolysis affords corresponding β,β-disubstituted 1-alkenylphosphine sulfides with high yield. The EtMgBr and Ti(O-iPr)4-catalyzed reaction of 2-alkynylamines, 1-alkynylphosphines, and 1-alkenylphosphine sulfides with Et2Zn in various solvents was studied. It has been found that the reaction of 2-alkynylamines and 1-alkynylphosphines in methylene chloride, hexane, toluene, benzene, and anisole leads to the selective formation of 2-alkenylamines and 1-alkenylphosphine oxides after oxidation with H2O2.
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Total citations:
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Citations from 2024:
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(54%)
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Kadikova R. N. et al. Carbozincation of Substituted 2-Alkynylamines, 1-Alkynylphosphines, 1-Alkynylphosphine Sulfides with Et2Zn in the Presence of Catalytic System of Ti(O-iPr)4 and EtMgBr // Catalysts. 2019. Vol. 9. No. 12. p. 1022.
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Kadikova R. N., Ramazanov I. R., Gabdullin A. M., Mozgovoi O. S., Dzhemilev U. M. Carbozincation of Substituted 2-Alkynylamines, 1-Alkynylphosphines, 1-Alkynylphosphine Sulfides with Et2Zn in the Presence of Catalytic System of Ti(O-iPr)4 and EtMgBr // Catalysts. 2019. Vol. 9. No. 12. p. 1022.
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RIS
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TY - JOUR
DO - 10.3390/catal9121022
UR - https://doi.org/10.3390/catal9121022
TI - Carbozincation of Substituted 2-Alkynylamines, 1-Alkynylphosphines, 1-Alkynylphosphine Sulfides with Et2Zn in the Presence of Catalytic System of Ti(O-iPr)4 and EtMgBr
T2 - Catalysts
AU - Kadikova, Rita N
AU - Ramazanov, Ilfir R.
AU - Gabdullin, Azat M.
AU - Mozgovoi, Oleg S
AU - Dzhemilev, Usein M.
PY - 2019
DA - 2019/12/04
PB - MDPI
SP - 1022
IS - 12
VL - 9
SN - 2073-4344
ER -
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@article{2019_Kadikova,
author = {Rita N Kadikova and Ilfir R. Ramazanov and Azat M. Gabdullin and Oleg S Mozgovoi and Usein M. Dzhemilev},
title = {Carbozincation of Substituted 2-Alkynylamines, 1-Alkynylphosphines, 1-Alkynylphosphine Sulfides with Et2Zn in the Presence of Catalytic System of Ti(O-iPr)4 and EtMgBr},
journal = {Catalysts},
year = {2019},
volume = {9},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/catal9121022},
number = {12},
pages = {1022},
doi = {10.3390/catal9121022}
}
Cite this
MLA
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Kadikova, Rita N., et al. “Carbozincation of Substituted 2-Alkynylamines, 1-Alkynylphosphines, 1-Alkynylphosphine Sulfides with Et2Zn in the Presence of Catalytic System of Ti(O-iPr)4 and EtMgBr.” Catalysts, vol. 9, no. 12, Dec. 2019, p. 1022. https://doi.org/10.3390/catal9121022.