Open Access
Halogen Bonding Provides Heterooctameric Supramolecular Aggregation of Diaryliodonium Thiocyanate
Vitalii V Suslonov
1
,
Troyana Yu Kissler
1
,
Daniil M Ivanov
1
,
Mekhman S. Yusubov
2
,
Pavel S. Postnikov
2, 3
,
Vadim Yu. Kukushkin
1, 4
3
Department of Solid State Engineering, Institute of Chemical Technology, 16628 Prague, Czech Republic
|
Publication type: Journal Article
Publication date: 2020-03-22
scimago Q2
wos Q2
SJR: 0.486
CiteScore: 5.0
Impact factor: 2.4
ISSN: 20734352, 01725076
Inorganic Chemistry
General Chemical Engineering
Condensed Matter Physics
General Materials Science
Abstract
The crystal structure of the newly synthesized 4-methoxyphenyl(phenyl)iodonium thiocyanate, [PhI(4-C6H4OMe)](SCN), represents the first example of 16-membered cyclic heterooctamer formed by halogen bonding between the iodonium cation and SCN−. Results of density functional theory (DFT) calculations followed by the topological analysis of the electron density distribution within the framework of the quantum theory of atoms in molecules (QTAIM) method at the ωB97XD/DZP-DKH level of theory reveal that energies of attractive intermolecular noncovalent interactions I···S and I···N (responsible for the formation of heterooctameric supramolecular clusters {PhI(4-C6H4OMe)}4·{SCN}4 in the solid state structure of [PhI(4-C6H4OMe)](SCN)) vary from 0.9 to 8.5 kcal/mol.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
|
|
|
Crystal Growth and Design
5 publications, 11.63%
|
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
5 publications, 11.63%
|
|
|
Journal of Structural Chemistry
4 publications, 9.3%
|
|
|
Координационная химия
4 publications, 9.3%
|
|
|
Polyhedron
3 publications, 6.98%
|
|
|
CrystEngComm
2 publications, 4.65%
|
|
|
Crystals
2 publications, 4.65%
|
|
|
Inorganica Chimica Acta
2 publications, 4.65%
|
|
|
Russian Journal of Inorganic Chemistry
2 publications, 4.65%
|
|
|
Organic Chemistry Frontiers
1 publication, 2.33%
|
|
|
Chemical Science
1 publication, 2.33%
|
|
|
Mendeleev Communications
1 publication, 2.33%
|
|
|
Russian Chemical Bulletin
1 publication, 2.33%
|
|
|
Nanomaterials
1 publication, 2.33%
|
|
|
Chemistry - An Asian Journal
1 publication, 2.33%
|
|
|
Liquid Chromatography of Synthetic Polymers
1 publication, 2.33%
|
|
|
Computational Materials Science
1 publication, 2.33%
|
|
|
Inorganic Chemistry Frontiers
1 publication, 2.33%
|
|
|
Surfaces and Interfaces
1 publication, 2.33%
|
|
|
Inorganic Chemistry Communication
1 publication, 2.33%
|
|
|
Inorganics
1 publication, 2.33%
|
|
|
Journal of Molecular Liquids
1 publication, 2.33%
|
|
|
Journal of Organic Chemistry
1 publication, 2.33%
|
|
|
1
2
3
4
5
|
Publishers
|
2
4
6
8
10
12
14
|
|
|
Pleiades Publishing
13 publications, 30.23%
|
|
|
Elsevier
9 publications, 20.93%
|
|
|
American Chemical Society (ACS)
6 publications, 13.95%
|
|
|
Royal Society of Chemistry (RSC)
5 publications, 11.63%
|
|
|
MDPI
4 publications, 9.3%
|
|
|
Springer Nature
2 publications, 4.65%
|
|
|
The Russian Academy of Sciences
2 publications, 4.65%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 2.33%
|
|
|
Wiley
1 publication, 2.33%
|
|
|
2
4
6
8
10
12
14
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
43
Total citations:
43
Citations from 2024:
18
(41%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Soldatova N. et al. Halogen Bonding Provides Heterooctameric Supramolecular Aggregation of Diaryliodonium Thiocyanate // Crystals. 2020. Vol. 10. No. 3. p. 230.
GOST all authors (up to 50)
Copy
Soldatova N., Suslonov V. V., Kissler T. Yu., Ivanov D. M., Novikov A. S., Yusubov M. S., Postnikov P. S., Kukushkin V. Y. Halogen Bonding Provides Heterooctameric Supramolecular Aggregation of Diaryliodonium Thiocyanate // Crystals. 2020. Vol. 10. No. 3. p. 230.
Cite this
RIS
Copy
TY - JOUR
DO - 10.3390/cryst10030230
UR - https://www.mdpi.com/2073-4352/10/3/230
TI - Halogen Bonding Provides Heterooctameric Supramolecular Aggregation of Diaryliodonium Thiocyanate
T2 - Crystals
AU - Soldatova, Natalia
AU - Suslonov, Vitalii V
AU - Kissler, Troyana Yu
AU - Ivanov, Daniil M
AU - Novikov, Alexander S.
AU - Yusubov, Mekhman S.
AU - Postnikov, Pavel S.
AU - Kukushkin, Vadim Yu.
PY - 2020
DA - 2020/03/22
PB - MDPI
SP - 230
IS - 3
VL - 10
SN - 2073-4352
SN - 0172-5076
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Soldatova,
author = {Natalia Soldatova and Vitalii V Suslonov and Troyana Yu Kissler and Daniil M Ivanov and Alexander S. Novikov and Mekhman S. Yusubov and Pavel S. Postnikov and Vadim Yu. Kukushkin},
title = {Halogen Bonding Provides Heterooctameric Supramolecular Aggregation of Diaryliodonium Thiocyanate},
journal = {Crystals},
year = {2020},
volume = {10},
publisher = {MDPI},
month = {mar},
url = {https://www.mdpi.com/2073-4352/10/3/230},
number = {3},
pages = {230},
doi = {10.3390/cryst10030230}
}
Cite this
MLA
Copy
Soldatova, Natalia, et al. “Halogen Bonding Provides Heterooctameric Supramolecular Aggregation of Diaryliodonium Thiocyanate.” Crystals, vol. 10, no. 3, Mar. 2020, p. 230. https://www.mdpi.com/2073-4352/10/3/230.