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Crystals

, volume 12 , issue 5 , pages 613

Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex

Mariya V Grudova ¹

Alexander S. Novikov ²

Alexey S. Kubasov ³

Victor N. Khrustalev ^{1, 4}

Anatoly A. Kirichuk ¹

Valentine G. Nenajdenko ⁵

Alexander Tskhovrebov ^{1, 6}

Hide authors affiliations Show authors affiliations: 6 affiliations

Research Institute of Chemistry, Peoples’ Friendship University of Russia, 6 Miklukho-Maklaya Street, 117198 Moscow, Russia |

Institute of Chemistry, Saint Petersburg State University, Universitetskaya nab. 7/9, 199034 Saint Petersburg, Russia |

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, 119071 Moscow, Russia |

⁴

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119334 Moscow, Russia |

⁵

Department of Chemistry, M. V. Lomonosov Moscow State University, 1, Leninskie Gory, 119991 Moscow, Russia |

⁶

N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Kosygina 4, 119991 Moscow, Russia |

Publication type: Journal Article

Publication date: 2022-04-26

MDPI

Crystals

scimago Q2

wos Q2

SJR: 0.486

CiteScore: 5.0

Impact factor: 2.4

ISSN: 20734352, 01725076

DOI: 10.3390/cryst12050613

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Inorganic Chemistry

General Chemical Engineering

Condensed Matter Physics

General Materials Science

Abstract

Gold(I) isocyanide complexes featuring Au···Au interactions attract considerable attention because of their tunable photophysical properties. Although the synthetic exploration of isocyanide gold(I) complexes seems reasonable, their structural diversity is mainly limited to linear gold(I) derivatives. The synthesis and structural characterization of cationic three-coordinate gold(I) mixed 2,2′-bipyridyl/isocyanide complex are presented here for the first time. Cationic gold species form supramolecular dimers in the solid state via attractive Au···Au interactions. The nature and energies of aurophilic contacts, which are responsible for dimerization in the solid state, were studied by DFT calculations together with QTAIM, ELF, RDG, and NCI techniques and Hirshfeld surface analysis. The estimated energy of the aurophilic interactions was 6.3 kcal/mol.

Found

6 citations

Novikov Alexander

🥼 🤝

PhD in Chemistry

411 publications, 8 100 citations, 251 reviews

h-index: 53

Saint Petersburg State University

Lomonosov Moscow State University

National Research University Higher School of Economics

Peoples' Friendship University of Russia

Research interests

Computational chemistry

Machine learning

Non-covalent Interactions

Quantum Chemistry

Reaction mechanisms

Supramolecular chemistry

1 citation

Gushchin Artem

DSc in Chemistry

145 publications, 1 813 citations, 63 reviews

h-index: 23

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

1 citation

Gorbunova Yuliya

DSc in Chemistry, professor, full member of the Russian Academy of Sciences

284 publications, 4 382 citations, 65 reviews

h-index: 34

Lomonosov Moscow State University

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Lanthanides

Supramolecular chemistry

Tetrapyrrolic compounds

1 citation

Doronina Evgeniya

PhD in Chemistry

41 publications, 432 citations

h-index: 13

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

1 citation

Birin Kirill

🥼 🤝

DSc in Chemistry

95 publications, 1 187 citations, 2 reviews

h-index: 19

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

MIREA — Russian Technological University

National Research University Higher School of Economics

Research interests

Catalysis

Coordination Chemistry

Green chemistry

Hybrid materials

Inorganic Chemistry

Metal-organic coordination polymers

NMR spectroscopy

Organic Chemistry

Organoelement chemistry

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Grudova M. V. et al. Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex // Crystals. 2022. Vol. 12. No. 5. p. 613.

GOST all authors (up to 50) Copy

Grudova M. V., Novikov A. S., Kubasov A. S., Khrustalev V. N., Kirichuk A. A., Nenajdenko V. G., Tskhovrebov A. Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex // Crystals. 2022. Vol. 12. No. 5. p. 613.

RIS |

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RIS Copy

TY - JOUR

DO - 10.3390/cryst12050613

UR - https://doi.org/10.3390/cryst12050613

TI - Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex

T2 - Crystals

AU - Grudova, Mariya V

AU - Novikov, Alexander S.

AU - Kubasov, Alexey S.

AU - Khrustalev, Victor N.

AU - Kirichuk, Anatoly A.

AU - Nenajdenko, Valentine G.

AU - Tskhovrebov, Alexander

PY - 2022

DA - 2022/04/26

PB - MDPI

SP - 613

IS - 5

VL - 12

SN - 2073-4352

SN - 0172-5076

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2022_Grudova,

author = {Mariya V Grudova and Alexander S. Novikov and Alexey S. Kubasov and Victor N. Khrustalev and Anatoly A. Kirichuk and Valentine G. Nenajdenko and Alexander Tskhovrebov},

title = {Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex},

journal = {Crystals},

year = {2022},

volume = {12},

publisher = {MDPI},

month = {apr},

url = {https://doi.org/10.3390/cryst12050613},

number = {5},

pages = {613},

doi = {10.3390/cryst12050613}

}

MLA

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MLA Copy

Grudova, Mariya V., et al. “Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex.” Crystals, vol. 12, no. 5, Apr. 2022, p. 613. https://doi.org/10.3390/cryst12050613.

Publisher

MDPI

Journal

Crystals

scimago Q2

wos Q2

SJR

0.486

CiteScore

5.0

Impact factor

2.4

ISSN

20734352 (Print, Electronic)

01725076 (Print)

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