Open Access

Energies

, volume 13 , issue 13 , pages 3393

Propane pre-reforming into methane-rich gas over ni catalyst: Experiment and kinetics elucidation via genetic algorithm

Sergey I Uskov ^{1, 2}

Dmitry Potemkin ^{1, 2, 3}

Leniza V Enikeeva ^{2, 4}

Pavel V Snytnikov ^{1, 2}

Irek M Gubaydullin ^{5, 6}

Vladimir A Sobyanin ¹

Hide authors affiliations Show authors affiliations: 6 affiliations

Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia |

Energy-Saving Catalytic Processes Laboratory, Novosibirsk State University, Pirogova St. 2, Novosibirsk 630090, Russia |

Department of Environmental Engineering, Novosibirsk State Technical University, Karl Marx Pr. 20, Novosibirsk 630073, Russia |

⁴

Mathematical Department, Ufa State Petroleum Technological University, Kosmonavtov St. 1, Ufa 450062, Russia |

⁵

Technological Department, Ufa State Petroleum Technological University, Kosmonavtov St. 1, Ufa 450062, Russia |

⁶

Institute of Petrochemistry and Catalysis of RAS, October Pr. 141, Ufa 450075, Russia |

Publication type: Journal Article

Publication date: 2020-07-02

MDPI

Energies

scimago Q1

wos Q3

SJR: 0.713

CiteScore: 7.3

Impact factor: 3.2

ISSN: 19961073

DOI: 10.3390/en13133393

Copy DOI

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Control and Optimization

Engineering (miscellaneous)

Energy (miscellaneous)

Abstract

Pre-reforming of propane was studied over an industrial nickel-chromium catalyst under pressures of 1 and 5 bar, at a low steam to carbon molar ratio of 1, in the temperature range of 220–380 °C and at flow rates of 4000 and 12,000 h−1. It was shown that propane conversion proceeded more efficiently at low pressure (1 atm) and temperatures above 350 °C. A genetic algorithm was applied to search for kinetic parameters better fitting experimental results in such a wide range of experimental conditions. Power law and Langmuir–Hinshelwood kinetics were considered. It was shown that only Langmuir–Hinshelwood type kinetics correctly described the experimental data and could be used to simulate the process of propane pre-reforming and predict propane conversion under the given reaction conditions. The significance of Langmuir–Hinshelwood kinetics increases under high pressure and temperatures below 350 °C.

Found

Top-30

Journals

	1 2
Reaction Kinetics, Mechanisms and Catalysis	Reaction Kinetics, Mechanisms and Catalysis, 2, 12.5% Reaction Kinetics, Mechanisms and Catalysis 2 publications, 12.5%
Journal of Physics: Conference Series	Journal of Physics: Conference Series, 2, 12.5% Journal of Physics: Conference Series 2 publications, 12.5%
Communications in Computer and Information Science	Communications in Computer and Information Science, 2, 12.5% Communications in Computer and Information Science 2 publications, 12.5%
Catalysts	Catalysts, 1, 6.25% Catalysts 1 publication, 6.25%
Energies	Energies, 1, 6.25% Energies 1 publication, 6.25%
Mathematics	Mathematics, 1, 6.25% Mathematics 1 publication, 6.25%
Catalysis Surveys from Asia	Catalysis Surveys from Asia, 1, 6.25% Catalysis Surveys from Asia 1 publication, 6.25%
ChemElectroChem	ChemElectroChem, 1, 6.25% ChemElectroChem 1 publication, 6.25%
Petroleum Chemistry	Petroleum Chemistry, 1, 6.25% Petroleum Chemistry 1 publication, 6.25%
Lecture Notes in Computer Science	Lecture Notes in Computer Science, 1, 6.25% Lecture Notes in Computer Science 1 publication, 6.25%
Lecture Notes in Networks and Systems	Lecture Notes in Networks and Systems, 1, 6.25% Lecture Notes in Networks and Systems 1 publication, 6.25%
Industrial & Engineering Chemistry Research	Industrial & Engineering Chemistry Research, 1, 6.25% Industrial & Engineering Chemistry Research 1 publication, 6.25%
	1 2

Publishers

	1 2 3 4 5 6 7
Springer Nature	Springer Nature, 7, 43.75% Springer Nature 7 publications, 43.75%
MDPI	MDPI, 3, 18.75% MDPI 3 publications, 18.75%
IOP Publishing	IOP Publishing, 2, 12.5% IOP Publishing 2 publications, 12.5%
Wiley	Wiley, 1, 6.25% Wiley 1 publication, 6.25%
Pleiades Publishing	Pleiades Publishing, 1, 6.25% Pleiades Publishing 1 publication, 6.25%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 6.25% American Chemical Society (ACS) 1 publication, 6.25%
	1 2 3 4 5 6 7

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

PDF

Metrics

Cite this

GOST |

Cite this

GOST Copy

Uskov S. I. et al. Propane pre-reforming into methane-rich gas over ni catalyst: Experiment and kinetics elucidation via genetic algorithm // Energies. 2020. Vol. 13. No. 13. p. 3393.

GOST all authors (up to 50) Copy

Uskov S. I., Potemkin D., Enikeeva L. V., Snytnikov P. V., Gubaydullin I. M., Sobyanin V. A. Propane pre-reforming into methane-rich gas over ni catalyst: Experiment and kinetics elucidation via genetic algorithm // Energies. 2020. Vol. 13. No. 13. p. 3393.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.3390/en13133393

UR - https://doi.org/10.3390/en13133393

TI - Propane pre-reforming into methane-rich gas over ni catalyst: Experiment and kinetics elucidation via genetic algorithm

T2 - Energies

AU - Uskov, Sergey I

AU - Potemkin, Dmitry

AU - Enikeeva, Leniza V

AU - Snytnikov, Pavel V

AU - Gubaydullin, Irek M

AU - Sobyanin, Vladimir A

PY - 2020

DA - 2020/07/02

PB - MDPI

SP - 3393

IS - 13

VL - 13

SN - 1996-1073

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2020_Uskov,

author = {Sergey I Uskov and Dmitry Potemkin and Leniza V Enikeeva and Pavel V Snytnikov and Irek M Gubaydullin and Vladimir A Sobyanin},

title = {Propane pre-reforming into methane-rich gas over ni catalyst: Experiment and kinetics elucidation via genetic algorithm},

journal = {Energies},

year = {2020},

volume = {13},

publisher = {MDPI},

month = {jul},

url = {https://doi.org/10.3390/en13133393},

number = {13},

pages = {3393},

doi = {10.3390/en13133393}

}

MLA

Cite this

MLA Copy

Uskov, Sergey I., et al. “Propane pre-reforming into methane-rich gas over ni catalyst: Experiment and kinetics elucidation via genetic algorithm.” Energies, vol. 13, no. 13, Jul. 2020, p. 3393. https://doi.org/10.3390/en13133393.

Publisher

MDPI

Journal

Energies

scimago Q1

wos Q3

SJR

0.713

CiteScore

7.3

Impact factor

3.2

ISSN

19961073 (Print, Electronic)

Profiles