Open Access
Boosting the Energetic Performance of Trinitromethyl-1,2,4-oxadiazole Moiety by Increasing Nitrogen-Oxygen in the Bridge
1
Publication type: Journal Article
Publication date: 2022-09-02
scimago Q1
wos Q1
SJR: 1.273
CiteScore: 9.0
Impact factor: 4.9
ISSN: 16616596, 14220067
PubMed ID:
36077400
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Computer Science Applications
Spectroscopy
Molecular Biology
General Medicine
Abstract
The trinitromethyl moiety is a useful group for the design and development of novel energetic compounds with high nitrogen and oxygen content. In this work, by using an improved nitration method, the dinitromethyl precursor was successfully nitrated to the trinitromethyl product (2), and its structure was thoroughly characterized by FTIR, NMR, elemental analysis, differential scanning calorimetry, and single-crystal X-ray diffraction. Compound 2 has a high density (1.897 g cm−3), high heat of formation (984.8 kJ mmol−1), and a high detonation performance (D: 9351 m s−1, P: 37.46 GPa) that may find useful applications in the field of high energy density materials.
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Total citations:
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Citations from 2024:
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(60%)
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Chen P. et al. Boosting the Energetic Performance of Trinitromethyl-1,2,4-oxadiazole Moiety by Increasing Nitrogen-Oxygen in the Bridge // International Journal of Molecular Sciences. 2022. Vol. 23. No. 17. p. 10002.
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Chen P., Dou H., He C., Pang S. Boosting the Energetic Performance of Trinitromethyl-1,2,4-oxadiazole Moiety by Increasing Nitrogen-Oxygen in the Bridge // International Journal of Molecular Sciences. 2022. Vol. 23. No. 17. p. 10002.
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RIS
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TY - JOUR
DO - 10.3390/ijms231710002
UR - https://doi.org/10.3390/ijms231710002
TI - Boosting the Energetic Performance of Trinitromethyl-1,2,4-oxadiazole Moiety by Increasing Nitrogen-Oxygen in the Bridge
T2 - International Journal of Molecular Sciences
AU - Chen, Peng
AU - Dou, Hui
AU - He, Chunlin
AU - Pang, Siping
PY - 2022
DA - 2022/09/02
PB - MDPI
SP - 10002
IS - 17
VL - 23
PMID - 36077400
SN - 1661-6596
SN - 1422-0067
ER -
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BibTex (up to 50 authors)
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@article{2022_Chen,
author = {Peng Chen and Hui Dou and Chunlin He and Siping Pang},
title = {Boosting the Energetic Performance of Trinitromethyl-1,2,4-oxadiazole Moiety by Increasing Nitrogen-Oxygen in the Bridge},
journal = {International Journal of Molecular Sciences},
year = {2022},
volume = {23},
publisher = {MDPI},
month = {sep},
url = {https://doi.org/10.3390/ijms231710002},
number = {17},
pages = {10002},
doi = {10.3390/ijms231710002}
}
Cite this
MLA
Copy
Chen, Peng, et al. “Boosting the Energetic Performance of Trinitromethyl-1,2,4-oxadiazole Moiety by Increasing Nitrogen-Oxygen in the Bridge.” International Journal of Molecular Sciences, vol. 23, no. 17, Sep. 2022, p. 10002. https://doi.org/10.3390/ijms231710002.