Open Access
New Carboxylate Anionic Sm-MOF: Synthesis, Structure and Effect of the Isomorphic Substitution of Sm3+ with Gd3+ and Tb3+ Ions on the Luminescent Properties
Anna A. Ivanova
1
,
Victoria E Gontcharenko
1, 2
,
Alexey M Lunev
1
,
Anastasia V Sidoruk
1
,
Ilya A Arkhipov
1
,
Ilya V. Taydakov
2
,
Yury A. Belousov
1, 2
Publication type: Journal Article
Publication date: 2022-07-25
Inorganic Chemistry
Abstract
Two new compounds, namely {(NMe2H2)}[Ln(TDA)(HCOO)] 0.5H2O, Ln = Sm3+ (Sm-TDA) and Gd3+ (Gd-TDA), where TDA3− is the anion of 1H-1,2,3-triazole-4,5-dicarboxylic acid (H3TDA), were synthesized by the solvothermal method in a DMF:H2O mixture. According to single-crystal X-ray diffraction data, the compounds are 3d-MOFs with an anionic lattice and dimethylammonium cations occupying part of the cavities. Based on these compounds, two series of mixed-metal complexes, [NMe2H2][SmxLn1-x(TDA)(HCOO)], (x = 0.9 (Sm0.9Ln0.1-TDA), x = 0.8 (Sm0.8-Ln0.2-TDA)…Sm0.02Ln0.98-TDA, Ln = Tb, Gd), were also obtained and characterized by powder XRD. The luminescent properties of the compounds were studied and it was shown that the resulting compounds are two- or three-component emitters with the possibility of fine color tuning by changing the intensities of fluorescence and phosphorescence of the ligand, as well as the luminescence of Sm3+ and Tb3+ f-ions.
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17
Total citations:
17
Citations from 2025:
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(17.65%)
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Ivanova A. A. et al. New Carboxylate Anionic Sm-MOF: Synthesis, Structure and Effect of the Isomorphic Substitution of Sm3+ with Gd3+ and Tb3+ Ions on the Luminescent Properties // Inorganics. 2022. Vol. 10. No. 8. p. 104.
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Ivanova A. A., Gontcharenko V. E., Lunev A. M., Sidoruk A. V., Arkhipov I. A., Taydakov I. V., Belousov Y. A. New Carboxylate Anionic Sm-MOF: Synthesis, Structure and Effect of the Isomorphic Substitution of Sm3+ with Gd3+ and Tb3+ Ions on the Luminescent Properties // Inorganics. 2022. Vol. 10. No. 8. p. 104.
Cite this
RIS
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TY - JOUR
DO - 10.3390/inorganics10080104
UR - https://www.mdpi.com/2304-6740/10/8/104
TI - New Carboxylate Anionic Sm-MOF: Synthesis, Structure and Effect of the Isomorphic Substitution of Sm3+ with Gd3+ and Tb3+ Ions on the Luminescent Properties
T2 - Inorganics
AU - Ivanova, Anna A.
AU - Gontcharenko, Victoria E
AU - Lunev, Alexey M
AU - Sidoruk, Anastasia V
AU - Arkhipov, Ilya A
AU - Taydakov, Ilya V.
AU - Belousov, Yury A.
PY - 2022
DA - 2022/07/25
PB - MDPI
SP - 104
IS - 8
VL - 10
SN - 2304-6740
ER -
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@article{2022_Ivanova,
author = {Anna A. Ivanova and Victoria E Gontcharenko and Alexey M Lunev and Anastasia V Sidoruk and Ilya A Arkhipov and Ilya V. Taydakov and Yury A. Belousov},
title = {New Carboxylate Anionic Sm-MOF: Synthesis, Structure and Effect of the Isomorphic Substitution of Sm3+ with Gd3+ and Tb3+ Ions on the Luminescent Properties},
journal = {Inorganics},
year = {2022},
volume = {10},
publisher = {MDPI},
month = {jul},
url = {https://www.mdpi.com/2304-6740/10/8/104},
number = {8},
pages = {104},
doi = {10.3390/inorganics10080104}
}
Cite this
MLA
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Ivanova, Anna A., et al. “New Carboxylate Anionic Sm-MOF: Synthesis, Structure and Effect of the Isomorphic Substitution of Sm3+ with Gd3+ and Tb3+ Ions on the Luminescent Properties.” Inorganics, vol. 10, no. 8, Jul. 2022, p. 104. https://www.mdpi.com/2304-6740/10/8/104.