Open Access
Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class
Vera V Voinova
1
,
Nikita A Selivanov
1
,
Ivan V Plyushchenko
2
,
Mikhail F Vokuev
2
,
Alexander Yu. Bykov
1
,
Ilya N. Klyukin
1
,
Alexander S. Novikov
3
,
Mikhail S. Grigoriev
4
,
Igor A Rodin
2
,
Publication type: Journal Article
Publication date: 2021-01-05
PubMed ID:
33466558
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
The novel members of the 1,2-diboraoxazoles family have been obtained. In the present work, we have carried out the intramolecular ring-closure reaction of borylated iminols of general type [B10H9N=C(OH)R]− (R = Me, Et, nPr, iPr, tBu, Ph, 4-Cl-Ph). This process is conducted in mild conditions with 83–87% yields. The solid-state structures of two salts of 1,2-diboraoxazoles were additionally investigated by X-ray crystallography. In addition, the phenomena of bonding interactions in the 1,2-diboraoxazole cycles have been theoretically studied by the Quantum Theory of Atoms in Molecules analysis. Several local and integral topological properties of the electron density involved in these interactions have been computed.
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33
Total citations:
33
Citations from 2024:
10
(30.3%)
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GOST
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Voinova V. V. et al. Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class // Molecules. 2021. Vol. 26. No. 1. p. 248.
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Voinova V. V., Selivanov N. A., Plyushchenko I. V., Vokuev M. F., Bykov A. Y., Klyukin I. N., Novikov A. S., Zhdanov A. P., Grigoriev M. S., Rodin I. A., Novikov A. S., Grigoriev M. S. Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class // Molecules. 2021. Vol. 26. No. 1. p. 248.
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RIS
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TY - JOUR
DO - 10.3390/molecules26010248
UR - https://doi.org/10.3390/molecules26010248
TI - Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class
T2 - Molecules
AU - Voinova, Vera V
AU - Selivanov, Nikita A
AU - Plyushchenko, Ivan V
AU - Vokuev, Mikhail F
AU - Bykov, Alexander Yu.
AU - Klyukin, Ilya N.
AU - Novikov, Alexander S.
AU - Zhdanov, Andrey P.
AU - Grigoriev, Mikhail S.
AU - Rodin, Igor A
AU - Novikov, Alexander S.
AU - Grigoriev, Mikhail S.
PY - 2021
DA - 2021/01/05
PB - MDPI
SP - 248
IS - 1
VL - 26
PMID - 33466558
SN - 1420-3049
ER -
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BibTex (up to 50 authors)
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@article{2021_Voinova,
author = {Vera V Voinova and Nikita A Selivanov and Ivan V Plyushchenko and Mikhail F Vokuev and Alexander Yu. Bykov and Ilya N. Klyukin and Alexander S. Novikov and Andrey P. Zhdanov and Mikhail S. Grigoriev and Igor A Rodin and Alexander S. Novikov and Mikhail S. Grigoriev},
title = {Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class},
journal = {Molecules},
year = {2021},
volume = {26},
publisher = {MDPI},
month = {jan},
url = {https://doi.org/10.3390/molecules26010248},
number = {1},
pages = {248},
doi = {10.3390/molecules26010248}
}
Cite this
MLA
Copy
Voinova, Vera V., et al. “Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class.” Molecules, vol. 26, no. 1, Jan. 2021, p. 248. https://doi.org/10.3390/molecules26010248.