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volume 26 issue 8 pages 2334

Catechol-Containing Schiff Bases on Thiacalixarene: Synthesis, Copper (II) Recognition, and Formation of Organic-Inorganic Copper-Based Materials

Publication typeJournal Article
Publication date2021-04-17
scimago Q1
wos Q2
SJR0.865
CiteScore8.6
Impact factor4.6
ISSN14203049
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract

For the first time, a series of catechol-containing Schiff bases, tetrasubstituted at the lower rim thiacalix[4]arene derivatives in three stereoisomeric forms, cone, partial cone, and 1,3-alternate, were synthesized. The structure of the obtained compounds was proved by modern physical methods, such as NMR, IR spectroscopy, and HRMS. Selective recognition (Kb difference by three orders of magnitude) of copper (II) cation in the series of d-metal cations (Cu2+, Ni2+, Co2+, Zn2+) was shown by UV-vis spectroscopy. Copper (II) ions are coordinated at the nitrogen atom of the imine group and the nearest oxygen atom of the catechol fragment in the thiacalixarene derivatives. High thermal stable organic-inorganic copper-based materials were obtained on the base of 1,3-alternate + Cu (II) complexes.

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GOST Copy
Padnya P. et al. Catechol-Containing Schiff Bases on Thiacalixarene: Synthesis, Copper (II) Recognition, and Formation of Organic-Inorganic Copper-Based Materials // Molecules. 2021. Vol. 26. No. 8. p. 2334.
GOST all authors (up to 50) Copy
Padnya P., Shibaeva K., Arsenyev M. V., Baryshnikova S., Terenteva O., Shiabiev I., Khannanov A., Boldyrev A., Gerasimov A., Grishaev D., Shtyrlin Y., Stoikov I. Catechol-Containing Schiff Bases on Thiacalixarene: Synthesis, Copper (II) Recognition, and Formation of Organic-Inorganic Copper-Based Materials // Molecules. 2021. Vol. 26. No. 8. p. 2334.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3390/molecules26082334
UR - https://doi.org/10.3390/molecules26082334
TI - Catechol-Containing Schiff Bases on Thiacalixarene: Synthesis, Copper (II) Recognition, and Formation of Organic-Inorganic Copper-Based Materials
T2 - Molecules
AU - Padnya, Pavel
AU - Shibaeva, Ksenia
AU - Arsenyev, Maxim V
AU - Baryshnikova, Svetlana
AU - Terenteva, Olga
AU - Shiabiev, Igor
AU - Khannanov, Artur
AU - Boldyrev, Artur
AU - Gerasimov, Alexander
AU - Grishaev, Denis
AU - Shtyrlin, Yurii
AU - Stoikov, Ivan
PY - 2021
DA - 2021/04/17
PB - MDPI
SP - 2334
IS - 8
VL - 26
PMID - 33920537
SN - 1420-3049
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Padnya,
author = {Pavel Padnya and Ksenia Shibaeva and Maxim V Arsenyev and Svetlana Baryshnikova and Olga Terenteva and Igor Shiabiev and Artur Khannanov and Artur Boldyrev and Alexander Gerasimov and Denis Grishaev and Yurii Shtyrlin and Ivan Stoikov},
title = {Catechol-Containing Schiff Bases on Thiacalixarene: Synthesis, Copper (II) Recognition, and Formation of Organic-Inorganic Copper-Based Materials},
journal = {Molecules},
year = {2021},
volume = {26},
publisher = {MDPI},
month = {apr},
url = {https://doi.org/10.3390/molecules26082334},
number = {8},
pages = {2334},
doi = {10.3390/molecules26082334}
}
MLA
Cite this
MLA Copy
Padnya, Pavel, et al. “Catechol-Containing Schiff Bases on Thiacalixarene: Synthesis, Copper (II) Recognition, and Formation of Organic-Inorganic Copper-Based Materials.” Molecules, vol. 26, no. 8, Apr. 2021, p. 2334. https://doi.org/10.3390/molecules26082334.